Synthesis and Evaluation of Ideal Core/Shell Quantum Dots with Precisely Controlled Shell Growth: Nonblinking, Single Photoluminescence Decay Channel, and Suppressed FRET

摘要

Due to the unique optical properties, colloidal quantum dots (QDs) are excellent candidates for developing next-generation display and solid-state lighting technologies. However, some factors including photoluminescence blinking and Forster resonance energy transfer (FRET) still affect their practical applications. Herein, a series of ZnCdSe-based core/shell QDs with low optical polydispersity have been successfully synthesized by a "low-temperature injection and high-temperature growth" precisely controlled method. The alloyed ZnCdSe core with a certain ratio of Cd and Zn was presynthesized first. Followed by accurate ZnS shell growth, the as-synthesized core/shell QDs are nonblinking with the nonblinking threshold volume of similar to 137 nm(3). The PL decay dynamics are all single-exponential for both QDs in solutions and close-packed solid films when ZnS shell thickness varying from 2 to 20 monolayers. FRET can be effectively suppressed after growing 10 monolayers of ZnS shell. All of these superb characteristics including nonblinking, single-exponential PL decay dynamics and suppressed FRET can be beneficial to high-quality QD-based light-emitting devices (QLEDs). By applying the ZnCdSe-based core/shell QDs with 10 monolayers ZnS shell, the highest external quantum efficiency of similar to 17% was reached, which could compare favorably with the highest efficiency of green QLEDs with traditional multilayered structures.