Synthesis of tungsten carbide nanopowders by direct carbonization of tungsten oxide and carbon: Effects of tungsten oxide source on phase structure and morphology evolution

摘要

In the paper, WC nanopowders are successfully prepared by carbothermal reduction method, and the effect of tungsten oxide source on the phase structure evolution and products properties of the as-synthesized WC nanopowders has been investigated. Four tungsten oxide powders are chosen as tungsten oxide sources, e.g., rods-like WO3, WO3 nanopartiles, WO3 micro-particles and WO2.9 micro-particles. Compared with other three tungsten oxide sources, the WO3 micro-particles possesses small particle size, less agglomerates and good dispersity and the uniform tungsten oxide-carbon mixture after ball milling can be easily obtained. The appropriate tungsten oxide source can result in lower processing temperature (<= 1200 degrees C) and shorter holding time (<= 3 h). Single-phase WC powders with average particle size of 100 nm and uniform particle distribution can be achieved by micro-particle-like WO3 at 1100 degrees C for 3 h. The as-prepared WC products by other three tungsten oxide sources exhibit problems of more aggregates, non-uniform particle size and large particle size (250 nm), respectively. In addition, the method can provide a facile, low-cost, efficient, and industrially feasible pathway for large scale preparation of WC nanopowders.