Diketopyrrolopyrrole‐based polymer fibrils formation by changing molecular conformation during film formation

Chen Liang; Zhao Kefeng; Cao Xinxiu; Liu Jiangang; Yu Xinhong; Han Yanchun

摘要

ABSTRACT > The microstructure of conjugated polymers film is strongly dependent on factors such as the conformation and the film formation processing. In this article, we show how to induce more planarization conformation of conjugated polymer backbone during film formation processing and finally leading to the fibrils formation of the cast film. The conjugated polymer we used is poly[[2,5‐bis(2‐octyldodecyl)‐2,3,5,6‐tetrahydro‐3,6‐dioxopyrrolo[3,4‐c]pyrrole‐1,4‐diyl]‐alt–[[2,2′‐(2,5‐thiophene)bis‐thieno[3,2‐b]thiophen]‐5,5′‐diyl]] (PDPPTT‐T). The main solvent is chloroform (CF), the aliphatic 1,8‐diiodooctane (DIO) is used as the additives, which has similar solubility parameter to the conjugated polymer side chain, is a bad solvent to the conjugated backbone and has a lower volatility than CF. Thus, during the film formation, chloroform was evaporated faster than the additive. After the chloroform evaporated completely, the side chain was still dissolved in the additive, which decreases the steric hindrance and improves planarization conformation of the conjugated backbone of PDPPTT‐T. Films processed using the aliphatic additives have fibrillar morphology while films cast from the CF solvent were featureless. TEM images reveal that the fibrils were about 30 nm in width and several hundred nanometers in length. The backbones of PDPPTT‐T were parallel to the long axis of fibrils. ? 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2018 , 56 , 1079–1086 </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”> <title type =“main”>抽象</ title> >缀合的聚合物膜的微观结构强烈依赖关于构象和薄膜形成处理等因素。在本文中，我们展示了如何在膜形成加工过程中诱导缀合的聚合物主链的更多平坦化构象，最后导致铸膜形成铸膜。我们使用的共轭聚合物是聚[[2,5-双二癸基）-2,3,5,6-四氢-3,6-二氧吡咯[3,4-C]吡咯-1,4-亚基] -ALT - [[2,2' - （2,5-噻吩）双-Thieno [3,2-B]噻吩] -5,5'-二基]（PDPPTT-T）。主要溶剂是氯仿（CF），脂族1,8-二碘辛烷（DIO）用作与共轭聚合物侧链具有相似的溶解度参数的添加剂，是缀合骨架的不良溶剂，挥发性较低比cf。因此，在成膜期间，氯仿比添加剂更快地蒸发。在氯仿完全蒸发之后，侧链仍然溶解在添加剂中，这降低了空间障碍并改善了PDPPTT-T的共轭骨干的平坦化构象。使用脂族添加剂加工的薄膜具有纤维状形态，而来自CF溶剂施放的薄膜无特征。 TEM图像显示，原纤维的宽度约为30nm，长度为几百纳米。 PDPPTT-T的骨干平行于纤维的长轴。还2018 Wiley期刊，Inc .J.Colom。 SCI。，B部分：聚合物。物理。 2018 </ b>， 56 </ i>，1079-1086 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-35627/'>《Journal of Polymer Science, Part B. Polymer Physics》</a> <b style="margin: 0 2px;">|</b><span>2018年第15期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Liang&option=202" target="_blank" rel="nofollow">Chen Liang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhao Kefeng&option=202" target="_blank" rel="nofollow">Zhao Kefeng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cao Xinxiu&option=202" target="_blank" rel="nofollow">Cao Xinxiu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Jiangang&option=202" target="_blank" rel="nofollow">Liu Jiangang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yu Xinhong&option=202" target="_blank" rel="nofollow">Yu Xinhong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Han Yanchun&option=202" target="_blank" rel="nofollow">Han Yanchun;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>State Key Laboratory of Polymer Physics and ChemistryChangchun Institute of Applied Chemistry Chinese Academy of Sciences 5625 Renmin StreetChangchun 130022 People's Republic of China;</p> <p>State Key Laboratory of Polymer Physics and ChemistryChangchun Institute of Applied Chemistry Chinese Academy of Sciences 5625 Renmin StreetChangchun 130022 People's Republic of China;</p> <p>State Key Laboratory of Polymer Physics and ChemistryChangchun Institute of Applied Chemistry Chinese Academy of Sciences 5625 Renmin StreetChangchun 130022 People's Republic of China;</p> <p>State Key Laboratory of Polymer Physics and ChemistryChangchun Institute of Applied Chemistry Chinese Academy of Sciences 5625 Renmin StreetChangchun 130022 People's Republic of China;</p> <p>State Key Laboratory of Polymer Physics and ChemistryChangchun Institute of Applied Chemistry Chinese Academy of Sciences 5625 Renmin StreetChangchun 130022 People's Republic of China;</p> <p>State Key Laboratory of Polymer Physics and ChemistryChangchun Institute of Applied Chemistry Chinese Academy of Sciences 5625 Renmin StreetChangchun 130022 People's Republic of China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1185.html" title="高分子化学（高聚物）">高分子化学（高聚物）;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=aliphatic additives&option=203" rel="nofollow">aliphatic additives;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=decrease the steric hindrance&option=203" rel="nofollow">decrease the steric hindrance;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=dissolving the side chain&option=203" rel="nofollow">dissolving the side chain;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=DPP‐based conjugated polymer fibrils&option=203" rel="nofollow">DPP‐based conjugated polymer fibrils;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=planarization conformation&option=203" rel="nofollow">planarization conformation;</a> </p> <div class="translation"> 机译：脂肪族添加剂;降低空间障碍;溶解侧链;基于DPP的共轭聚合物原纤维;平面化构象; 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