Pore structure characteristics and hydrocarbon generation potential of middle Jurassic lacustrine source rocks in the Yuka depression, Qaidam Basin, NW China: Implications from petrographic and organic geochemical analyses

摘要

The Yuka depression is one of the most important energy production bases in the Qaindam Basin. Although shales in the 7th member of the Dameigou Formation (J(2)d(7)) are key members of Middle Jurassic Petroleum System, organic geochemistry and petrography of different rock facies have not been fully analyzed. In this study we evaluate hydrocarbon generation potential of the J(2)d(7) by applying integrated petrographic, geochemical and mineralogical analyses. In addition, pore structure is characterized using field emission scanning electron microscopy (SEM), CO2 and N-2 physisorption. Results indicate that mudstone, carbonaceous-mudstone and siltstone have total organic carbon (TOC) values of 2.64%, 5.61% and 0.48%, respectively, as well as variations in the hydrogen index (HI). Kerogen types are mainly Type III, with maturity varying from marginally mature to mature. Notably, excess methane adsorption capacities were higher in the carbonaceous-mudstone sample (4.66 cm(3)/g) than in the mudstone sample (1.78 cm(3)/g). Primary minerals in the mudstone were quartz and clay; kaolinite, illite and illite/smectite (I/S) were the dominant clay minerals. Clay minerals and TOC content, as well as positive correlations between illite, I/S and mesopore SSA, were factors controlling pore structure development; in contrast, kaolinite contents were negatively correlated with SSA. Liptinite is the dominant maceral composition and a high content of C-29 regular sterane in the carbonaceous-mudstones suggests primary higher-plant input, associated with a low gammacerane index (0.28-0.32) and a high pristane/phytane (Pr/Ph) ratio (3.02-3.96). Petrographic and geochemical results indicate an alternating depositional environment across suboxic semi-saline to oxic fresh water changes. Higher-plants were predominant and a small quantity of algae were preserved through in-situ accumulation and migration during shale development; an oxic water column with carbonaceous-mudstone was also present. Although organic matter was marginally mature to mature, the abundance of liptinite (average of 63%) was derived from higher-plants, possibly being the primary materials producing gaseous hydrocarbons.