Element geochemical characteristics and formation environment for the roof, floor and gangue of coal seams in the Gujiao mining area, Xishan coalfield, China

摘要

The roof, floor and gangue samples of coal seams were collected from a borehole in the Gujiao mining area. The vertical distribution of major elements, trace elements and rare earth elements (REEs) was tested through X-ray fluorescence spectrometry and inductively coupled plasma-mass spectrometry (ICP-MS). The formation environment and material source of the strata were analysed. The results showed that the major elements of the coal seam roof, floor and gangue are Si and Al, followed by Fe, K, and Ti. In the Shanxi Formation, Sn, B, Ta, Bi, Th, U, Li, Be, Nb, In, Cs and Hf are enriched. In the Taiyuan Formation, B, Bi, U, Li, Sr, Mo and Sb are enriched. Sn, B, Th, U, and Be of the Shanxi Formation and B, U, Mo, and Sb of Taiyuan Formation are enriched hazardous elements. The ratios of Sr/Ba, U/Th, Ni/Co and V/Cr could indicate the paleosalinity and redox conditions. The Shanxi Formation was mainly formed in an oxic environment. The roof and floor of the No. 7 coal and the roof of the No. 8 coal are limestone, indicating anoxic and suboxic to dysoxic environments. The lithology of the Shanxi Formation and Taiyuan Formation material source is complex, including sedimentary rocks, granite and alkaline basalt. Most samples are distributed at the intersection of the granite and alkaline basalt, indicating dual sourcing from the granite and alkaline basalt.