A new high frequency dynamic mechanical analysis system: An approach to direct high frequency testing of tire tread rubber

摘要

Dynamic Mechanical Analysis (DMA) systems are measurement devices for obtaining master curves and complex modules of viscoelastic materials, such as rubbers. The conventional DMAs measurement systems in market have several limitations, which restrict their ability for operating at high frequencies. Thus, Williams, Landel and Ferry (WLF) relation is used to produce master curves and predict the material properties at high frequencies. In conventional DMAs, experiments are done in a range of temperatures, and then a master curve is made for a chosen reference temperature by shifting the measurements data to high frequencies. Therefore, the obtained results, which are not based on direct measurements, can be inaccurate. In order to overcome this problem a new simple shear high-frequency DMA (HFDMA) system is designed and built to directly measure the dynamic mechanical properties of viscoelastic material at high frequencies and the strain levels sufficient for tire manufacturers. The new HFDMA can be used to test any viscoelastic materials which have glass transmission temperature (Tg) lower than mom temperature (about 23 degrees C) such as the Styrene-butadiene rubber (SBR). The SBR is the base material for tire tread. The designing process of this new HFDMA is presented in this paper. The rubber specimen shape is chosen by taking into account the shear elastic wave effect, bending, buckling effect and heat generation in the specimen. The repeatability test is accomplished to ensure that the results obtained from the new HFDMA are repeatable and the repeatability uncertainty is about 0.04%. The new HFDMA is validated by comparing to the direct test results of conventional DMA at 100 Hz. The direct high frequency (5 kHz) complex shear modulus and damping factor are compared with the master curve of the conventional DMA developed by the use of WLF relation for SBR. This comparison revealed that the complex shear modulus and damping factor of the SBR obtained from the HFDMA at 5 kHz and 0.05% strain amplitude are about 7% and 6.5% higher than those obtained from the conventional DMA, respectively.