Research progress on large-area perovskite thin films and solar modules

摘要

Organometal halide perovskites have exhibited a bright future as photovoltaic semiconductor in next generation solar cells due to their unique and promising physicochemical properties. Over the past few years, we have witnessed a tremendous progress of efficiency record evolution of perovskite solar cells (PSCs). Up to now, the highest efficiency record of PSCs has reached 22.1%; however, it was achieved at a very small device area of <0.1?cm2. With the device area increasing to mini-module scale, the efficiency record dropped dramatically. The inherent causes are mainly ascribed to inadequate quality control of large-area perovskite thin films and insufficient optimization of solar module design. In current stage of PSCs research and development, to overcome these two obstacles is in urgent need before this new technology could realize scale-up industrialization. Herein, we present an overview of recently developed strategies for preparing large-area perovskite thin films and perovskite solar modules (PSMs). At last, cost analysis and future application directions of PSMs have also been discussed.Graphical abstractDisplay OmittedHighlights?Effective methods for the deposition of large-area perovskite thin films (≥1?cm2) have been systematically reviewed.?Strategies for fabricating perovskite solar modules have been discussed.?The efficiency drop caused by the enhancement of electrode resistance for PSMs connected in series has been analyzed.?The future application directions of perovskite solar cells have been introduced.