Nanoparticles Formed onto/into Halloysite Clay Tubules: Architectural Synthesis and Applications

Vinokurov Vladimir A.; Stavitskaya Anna V.; Glotov Aleksandr P.; Novikov Andrei A.; Zolotukhina Anna V.; Kotelev Mikhail S.; Gushchin Pawel A.; Ivanov Evgenii V.; Darrat Yusuf; Lvov Yuri M.

摘要

Abstract >Nanoparticles, being objects with high surface area are prone to agglomeration. Immobilization onto solid supports is a promising method to increase their stability and it allows for scalable industrial applications, such as metal nanoparticles adsorbed to mesoporous ceramic carriers. Tubular nanoclay – halloysite – can be an efficient solid support, enabling the fast and practical architectural (inside / outside) synthesis of stable metal nanoparticles. The obtained halloysite‐nanoparticle composites can be employed as advanced catalysts, ion‐conducting membrane modifiers, inorganic pigments, and optical markers for biomedical studies. Here, we discuss the possibilities to synthesize halloysite decorated with metal, metal chalcogenide, and carbon nanoparticles, and to use these materials in various fields, especially in catalysis and petroleum refinery. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</标题> >纳米粒子，具有高表面积的物体容易凝聚。固定到固体载体上是一种提高其稳定性的有希望的方法，并且它允许可扩展的工业应用，例如吸附到中孔陶瓷载体的金属纳米颗粒。管状纳米铅 - 霍罗铁矿 - 可以是有效的坚固的支持，使稳定的金属纳米粒子的快速和实用的建筑（内/外）合成。所得卤素矿纳米颗粒复合材料可用作催化剂，离子导电膜改性剂，无机颜料和生物医学研究的光学标志物。在这里，我们讨论了合成用金属，金属硫属元素和碳纳米粒子装饰的Halloysite的可能性，并在各种领域中使用这些材料，特别是在催化和石油炼油厂中。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16132/'>《Chemical record》</a> <b style="margin: 0 2px;">|</b><span>2018年第8期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Vinokurov Vladimir A.&option=202" target="_blank" rel="nofollow">Vinokurov Vladimir A.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Stavitskaya Anna V.&option=202" target="_blank" rel="nofollow">Stavitskaya Anna V.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Glotov Aleksandr P.&option=202" target="_blank" rel="nofollow">Glotov Aleksandr P.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Novikov Andrei A.&option=202" target="_blank" rel="nofollow">Novikov Andrei A.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zolotukhina Anna V.&option=202" target="_blank" rel="nofollow">Zolotukhina Anna V.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kotelev Mikhail S.&option=202" target="_blank" rel="nofollow">Kotelev Mikhail S.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gushchin Pawel A.&option=202" target="_blank" rel="nofollow">Gushchin Pawel A.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ivanov Evgenii V.&option=202" target="_blank" rel="nofollow">Ivanov Evgenii V.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Darrat Yusuf&option=202" target="_blank" rel="nofollow">Darrat Yusuf;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lvov Yuri M.&option=202" target="_blank" rel="nofollow">Lvov Yuri M.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Physical and Colloid ChemistryGubkin University65-1 Leninsky prospect Moscow Russia 119991;</p> <p>Department of Physical and Colloid ChemistryGubkin University65-1 Leninsky prospect Moscow Russia 119991;</p> <p>Department of Physical and Colloid ChemistryGubkin University65-1 Leninsky prospect Moscow Russia 119991;</p> <p>Department of Physical and Colloid ChemistryGubkin University65-1 Leninsky prospect Moscow Russia 119991;</p> <p>Department of ChemistryLomonosov Moscow State University1-3 Leninskiye Gory Moscow Russia 119991;</p> <p>Department of Physical and Colloid ChemistryGubkin University65-1 Leninsky prospect Moscow Russia 119991;</p> <p>Department of Physical and Colloid ChemistryGubkin University65-1 Leninsky prospect Moscow Russia 119991;</p> <p>Department of Physical and Colloid ChemistryGubkin University65-1 Leninsky prospect Moscow Russia 119991;</p> <p>Institute for MicromanufacturingLouisiana Tech University911 Hergot Ave. Ruston LA 71272 USA;</p> <p>Department of Physical and Colloid ChemistryGubkin University65-1 Leninsky prospect Moscow Russia 119991;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/159.html" title="化学">化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Halloysite&option=203" rel="nofollow">Halloysite;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=quantum dots&option=203" rel="nofollow">quantum dots;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=core-shell nanosystems&option=203" rel="nofollow">core-shell nanosystems;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Schiff bases&option=203" rel="nofollow">Schiff bases;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=catalysis&option=203" rel="nofollow">catalysis;</a> </p> <div class="translation"> 机译：Halloysite;量子点;核心壳纳米系统;Schiff Bases;催化; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li 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class="enjiyixqcontent" href="/patent-detail/06120111180501.html">一步合成团簇型钯铜纳米粒子的方法及团簇型钯铜纳米粒子的应用</a> <b>[P]</b> . <span> 中国专利： CN108672717A </span> <span> . 2018-10-19</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130414564445.html">SYNTHESIS OF SUPPORTED NIPT BIMETALLIC NANOPARTICLES, METHODS FOR CONTROLLING THE SURFACE COVERAGE OF Ni NANOPARTICLES WITH Pt, METHODS OF MAKING NIPT MULTILAYER CORE-SHELL STRUCTURES AND APPLICATION OF THE SUPPORTED CATALYSTS FOR CO<Sub>2</Sub> REFORMING</a> <b>[P]</b> . <span> 外国专利：  WO2015092551A2 </span> <span> . 2015-06-25</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：支持的Nipt双金属纳米粒子的合成，用Pt控制Ni纳米粒子的表面覆盖的方法，制备Nipt多层核壳结构的方法以及支持的CO <sub> 2 </ Sub>重整催化剂的应用 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130411009100.html">SYNTHESIS OF 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