Sol‐Gel Synthesis and Fine Characterization of Hierarchically Porous and Multifunctional Silica‐Based Membranes

Ayral André

摘要

Abstract >Rational design of thin films for improving their functional properties can result in complex architectures. This issue will be here illustrated in the case of sol‐gel derived hierarchically porous and multifunctional silica‐based membranes. Thin silica layers with isolated and randomly distributed macropores, isolated and ordered mesopores and an interconnected microporosity in the silica walls are thus obtained by combining different synthesis strategies. The impact of the overall porosity and of the pore size distribution on the mechanical properties of these layers is investigated coupling experimental measurements and numerical simulation. The extra porosity is used for providing a catalytic functionality by inserting Pt nanoparticles at predefined locations. Two methods are implemented to control the spatial distribution of the catalytic nanoparticles either in the mesopores or in the macropores. The catalytic performance of the resulting materials is tested. Organosilica thin films with isolated and ordered mesopores and an interconnected microporosity in the walls are also prepared and characterized in terms of adsorption and gas permeation. Numerical simulation of adsorption appears as a promising tool for understanding and predicting the properties of such films. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >薄膜的合理设计，用于提高其功能性质可能导致复杂的架构。这里将在溶胶 - 凝胶衍生的分层多孔和多官能二氧化硅基膜的情况下说明该问题。通过组合不同的合成策略，因此通过组合不同的合成策略来获得具有分离和随机分布的MASOPORE，分离和有序的巨孔的薄二氧化硅层和二氧化硅壁中的互连微孔。研究了整体孔隙率和孔径分布对这些层的力学性能的影响是耦合实验测量和数值模拟。额外的孔隙率用于通过在预定位置插入Pt纳米颗粒来提供催化功能。实施了两种方法以控制催化纳米颗粒的空间分布在中孔中或大孔中。测试所得材料的催化性能。有机硅薄膜与隔离和有序的中孔和壁中的相互连接的微孔，在吸附和气体渗透方面也表征。吸附的数值模拟表现为有希望的工具，用于理解和预测这种薄膜的性质。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16132/'>《Chemical record》</a> <b style="margin: 0 2px;">|</b><span>2018年第8期</span><b style="margin: 0 2px;">|</b><span>共13页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ayral André&option=202" target="_blank" rel="nofollow">Ayral André;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Institut Européen des MembranesCNRS/ENSCM/Université de Montpellier CC0472 place Eugène Bataillon 34095 Montpellier cedex 5 France;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/159.html" title="化学">化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Silica&option=203" rel="nofollow">Silica;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hierarchical porosity&option=203" rel="nofollow">hierarchical porosity;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=multifunctional membranes&option=203" rel="nofollow">multifunctional membranes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=fine characterization&option=203" rel="nofollow">fine characterization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=numerical simulation&option=203" rel="nofollow">numerical simulation;</a> </p> <div class="translation"> 机译：二氧化硅;等级孔隙率;多功能膜;精细表征;数值模拟; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022079928.html">Sol‐Gel Synthesis and Fine Characterization of Hierarchically Porous and Multifunctional Silica‐Based Membranes</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ayral André&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ayral André </a> <a href="/journal-foreign-16132/" target="_blank" rel="nofollow" class="tuijian_authcolor">Chemical record .</a> <span>2018</span><span>,第7a8期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：溶胶 - 凝胶合成和分层多孔和多功能二氧化硅基膜的精细表征</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704014794730.html">One pot synthesis of hierarchical porous silica membrane material with dispersed Pt nanoparticles using a microwave-assisted sol-gel route</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Christelle Yacou&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Christelle Yacou,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Marie-Laure Fontaine&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Marie-Laure Fontaine,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Andre Ayral&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Andre Ayral </a> <a href="/journal-foreign-35179/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology .</a> <span>2008</span><span>,第36期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：微波辅助溶胶-凝胶法一锅法合成具有分散的Pt纳米颗粒的分级多孔二氧化硅膜材料</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704015369920.html">Preparation and characterization of porous silica films by a modified base-cagalyzed sol-gel process containing PVA:I.the precursor solution synthesis</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Y.Liu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Y.Liu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=H.Chen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">H.Chen,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=L.Zhang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">L.Zhang,</a> <a href="/journal-foreign-35806/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Sol-Gel Science and Technology .</a> <span>2002</span><span>,第2期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：含PVA的改性碱钙化溶胶-凝胶法制备二氧化硅多孔膜及其表征。前体溶液合成</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-257390_thesis/0705010556797.html">Characterization of sulfonated poly (arylene ether sulfone)(SPAES)/silica-phosphate sol-gel composite membrane: the effect of sol-gel composition</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hae Young Hwang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hae Young Hwang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Deuk Ju Kim&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Deuk Ju Kim,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Young Taik Hong&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Young Taik Hong </a> <a href="/conference-foreign-257390/" target="_blank" rel="nofollow" class="tuijian_authcolor">North American Membrane Society Annual Meeting .</a> <span>2010</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：磺化聚（亚芳醚砜）（Spaes）/二氧化硅磷酸溶胶 - 凝胶复合膜的表征：溶胶 - 凝胶组合物的作用</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061741712.html">Sol-gel synthesis of magnesium silicate thin films and powders and synthesis and characterization of nickel-alumina composites</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jones, Steven Alan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jones, Steven Alan </a> <span>1995</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：硅酸镁薄膜和粉末的溶胶-凝胶合成及镍铝复合材料的合成与表征</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040007220535.html">Silica Containing Composite Anion Exchange Membranes by Sol–Gel Synthesis: A Short Review</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Emanuela Sgreccia&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Emanuela Sgreccia,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Riccardo Narducci&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Riccardo Narducci,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Philippe Knauth&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Philippe Knauth,</a> <span>2021</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：二氧化硅通过溶胶 - 凝胶合成含有复合阴离子交换膜：简要审查</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/010008631809.html ">Polymeric-silica-based sols for membrane modification applications: sol-gel synthesis and characterization with SAXS</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=de Lange, Rob&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">de Lange, Rob,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=de Lange, R.S.A.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">de Lange, R.S.A.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hekkink, J.H.A.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hekkink, J.H.A.,</a> <span>1995</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于膜改性应用的基于聚合物二氧化硅的溶胶：溶胶-凝胶合成和SAXS表征</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201295838779.html">溶胶-凝胶法制备纳米二氧化硅溶胶和多孔二氧化硅薄膜</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=殷明志&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 殷明志</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=姚熹&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,姚熹</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=吴小清&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,吴小清</a> <span> <a href="/journal-cn-57285/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 硅酸盐学报 </a> </span> <span> . 2002</span><span>,第6期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_glass-enamel_thesis/0201252028509.html">溶胶-凝胶法制备纳米多孔二氧化硅减反膜的研究进展</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李春华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李春华</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=姜宏&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,姜宏</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赵会峰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,赵会峰</a> <span> <a href="/journal-cn-9039/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 玻璃与搪瓷 </a> </span> <span> . 2014</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_electroplating-finishing_thesis/0201275741102.html">一步溶胶−凝胶法制备乙烯基功能化二氧化硅微球及其表征</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=高爱环&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 高爱环</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郝向英&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,郝向英</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=操江飞&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,操江飞</a> <span> <a href="/journal-cn-9047/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 电镀与涂饰 </a> </span> <span> . 2019</span><span>,第016期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_china-synthetic-rubber-industry_thesis/0201246703713.html">溶胶-凝胶法聚丙烯酸丁酯/二氧化硅杂化材料弹性体的制备与表征</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=麦东东&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 麦东东</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王炼石&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王炼石</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张安强&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张安强</a> <span> <a href="/journal-cn-9131/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 合成橡胶工业 </a> </span> <span> . 2010</span><span>,第002期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-shaanxi-normal-university-natural-science-edition_thesis/0201250689358.html">纳米银粒子-二氧化硅复合颗粒溶胶-凝胶的制备与表征</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=马少华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 马少华</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李贵安&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李贵安</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张玉荣&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张玉荣</a> <span> <a href="/journal-cn-4713/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 陕西师范大学学报（自然科学版） </a> </span> <span> . 2008</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-4267_thesis/020221023452.html">溶胶—凝胶法制备纳米二氧化硅溶胶和多孔二氧化硅薄膜</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=YIN Mingzhi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . YIN Mingzhi</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=殷明志&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,殷明志</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=YIAO Xi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,YIAO Xi</a> <span> <a href="/conference-cn-4267/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2013年全国无机硅化物行业年会暨行业“调结构、转方式、稳增长”经验交流会 </a> <span> <span> . 2013</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314849557.html">纳米多孔二氧化硅光学功能薄膜的溶胶-凝胶法制备与性能研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=肖尧&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 肖尧</a> <span> . 2017</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120113330085.html">二氧化硅溶胶、使用它制造的二氧化硅气凝胶毡和制造二氧化硅气凝胶毡的方法</a> <b>[P]</b> . <span> 中国专利： CN113382962A </span> <span> . 2021-09-10</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120112010764.html">二氧化硅溶胶、二氧化硅溶胶凝胶复合岩棉保温材料及其制备方法</a> <b>[P]</b> . <span> 中国专利： CN111994912A </span> <span> . 2020-11-27</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130416741956.html">Method for producing porous biodegradable synthetic polymer/sol-gel derived silica membrane and porous biodegradable synthetic polymer/sol-gel derived silica membrane manufactured thereby</a> <b>[P]</b> . <span> 外国专利：  KR101347726B1 </span> <span> . 2014-01-22</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：多孔质可生物降解的合成聚合物/溶胶-凝胶衍生的二氧化硅膜的生产方法和由此制备的多孔质可生物降解的合成聚合物/溶胶-凝胶衍生的二氧化硅膜 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130419423180.html">METHOD FOR PRODUCING POROUS BIODEGRADABLE SYNTHETIC POLYMER/SOL-GEL DERIVED SILICA MEMBRANE AND POROUS BIODEGRADABLE SYNTHETIC POLYMER/SOL-GEL DERIVED SILICA MEMBRANE MANUFACTURED THEREBY</a> <b>[P]</b> . <span> 外国专利：  KR20130090235A </span> <span> . 2013-08-13</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：制备多孔可生物合成的聚合物/溶胶-凝胶衍生的二氧化硅膜的方法和由此制备的多孔可生物合成的聚合物/溶胶-凝胶衍生的二氧化硅膜的方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130418699927.html">Adhesion of the membrane of the silica sol on the gas separation membrane null porous base material which includes</a> <b>[P]</b> . <span> 外国专利：  JP5497297B2 </span> <span> . 2014-05-21</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：二氧化硅溶胶的膜在气体分离膜上的粘附力为零，多孔基质材料包括 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704022079928','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704022079928down" data-source="7," data-out-id="ZO/TKVJGXaOEnTDFa9iDjgEkjJ5KyFzgM2rhTzh0JiCx2qzoWznLUOfL33ecj8ab," data-f-source-id="7" data-title="Sol‐Gel Synthesis and Fine Characterization of Hierarchically Porous and Multifunctional Silica‐Based Membranes" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="16132" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Sol‐Gel Synthesis and Fine Characterization of Hierarchically Porous and Multifunctional Silica‐Based Membranes"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.8"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.8"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>