Driving the Crystallization of Zeolites

Lu Peng; Villaescusa L. A.; Camblor M. A.

摘要

Abstract >The synthesis of zeolites with new structures and/or improved properties heavily relies on trial and error efforts that are not entirely blind, as the large empirical background accumulated for the last 7 decades can be, to some extent, rationalized and purposefully used to make new materials. The so‐called structure‐directing factors may be combined to promote (or frustrate) the crystallization of a particular structure. This personal account opens with the concept of geoinspiration, as suggested by Prof. Ruiz‐Hitzky, and its application to zeolite synthesis. We then provide a concise overview of structure‐direction in the synthesis of zeolites and detail examples, both new and from the literature, on how they can be combined to drive the crystallization towards (or away from) structures displaying particular features. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >具有新结构和/或改进属性的沸石的合成严重依赖于试验和错误努力这并不完全失明，因为在过去7个十年中积累的大型经验背景可以在某种程度上合理化和有目的地用于制作新材料。可以将所谓的结构引导因子组合以促进特定结构的结晶（或挫败）。这款个人账户与地产灭的概念开口，如鲁智人教授的建议，并在沸石综合的应用中提出。然后，我们在沸石和细节示例的合成中提供了一种简明的结构方向，包括新的和来自文献，可以将它们的组合方式和从文献组合起来，以使结晶朝向（或远离）结构显示特定特征的结构。</ p > </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16132/'>《Chemical record》</a> <b style="margin: 0 2px;">|</b><span>2018年第8期</span><b style="margin: 0 2px;">|</b><span>共11页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lu Peng&option=202" target="_blank" rel="nofollow">Lu Peng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Villaescusa L. A.&option=202" target="_blank" rel="nofollow">Villaescusa L. A.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Camblor M. A.&option=202" target="_blank" rel="nofollow">Camblor M. A.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Institute of Materials Science of Madrid (ICMM)Consejo Superior de Investigaciones Científicas (CSIC)c/ Sor Juana Inés de la Cruz 3 Madrid Spain;</p> <p>Instituto Interuniversitario de Investigación de Reconocimiento Molecular y Desarrollo Tecnológico (IDM)Universitat Politècnica de València Universitat de ValènciaSpain;</p> <p>Institute of Materials Science of Madrid (ICMM)Consejo Superior de Investigaciones Científicas (CSIC)c/ Sor Juana Inés de la Cruz 3 Madrid Spain;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/159.html" title="化学">化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zeolites&option=203" rel="nofollow">Zeolites;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Synthesis&option=203" rel="nofollow">Synthesis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Structure-direction&option=203" rel="nofollow">Structure-direction;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Geoinspiration&option=203" rel="nofollow">Geoinspiration;</a> </p> <div class="translation"> 机译：沸石;合成;结构方向;土工悬浮液; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022079854.html">Driving the Crystallization of Zeolites</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lu Peng&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Lu Peng,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Villaescusa L. 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张勇光&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张勇光</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李晓旭&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李晓旭</a> <span> <a href="/conference-cn-9332/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十一届全国化学工艺学术年会 </a> <span> <span> . 2011</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314122199.html">全硅沸石与有机分子相互作用的模拟计算及低硅沸石结晶行为的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=林德昌&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 林德昌</a> <span> . 2003</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120338985.html">微孔结晶沸石材料(沸石ITQ－22),其合成方法及其作为催化剂的应用</a> <b>[P]</b> . <span> 中国专利： CN100352766C </span> <span> . 2007.12.05</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120104869574.html">微孔结晶沸石材料(沸石ITQ－22),其合成方法及其作为催化剂的应用</a> <b>[P]</b> . <span> 中国专利： CN1671622A </span> <span> . 2005-09-21</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130439102982.html">Production of enclosed zeolite layers for use in e.g. catalysis or separation membranes, comprises first seed crystallization on carrier followed by further crystallization using different synthesis solution or gel</a> <b>[P]</b> . <span> 外国专利：  DE10304322A1 </span> <span> . 2004-11-18</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：封闭的沸石层的生产用于例如催化或分离膜，包括首先在载体上进行晶种结晶，然后使用不同的合成溶液或凝胶进一步晶化 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130448213962.html">Production of zeolite, e.g. titanium zeolite, useful as catalyst (support), sorbent, pigment or filler for plastics, involves crystallizing solid from precursor(s) and direct drying of reaction mixture</a> <b>[P]</b> . <span> 外国专利：  DE19939416A1 </span> <span> . 2001-02-22</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：沸石的生产，例如用作聚合物的催化剂（载体），吸附剂，颜料或填料的钛沸石，涉及从前体中结晶出固体并直接干燥反应混合物 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130458437328.html">METHOD FOR REDUClNG AUTOMOTlVE NOx EMISSIONS l LEAN BURN lNTERNAL COM-BUSTION ENGlNE EXHAUST USl A TRANSITION Using transition metal-containing zeolites that crystallize in situ METAL-CONTAINTNG ZEOLITE CATALYST WHlCH IS lN-SITU CRYSTALlLIZED)</a> <b>[P]</b> . <span> 外国专利：  KR950702866A </span> <span> . 1995-08-23</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：减少易燃的NOx排放的方法l稀薄的燃烧燃烧尾气使用一种过渡技术，该过渡技术使用的是含过渡金属的沸石，这些沸石在原位结晶的情况下会原位结晶成金属的沸石催化剂。 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704022079854','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img 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