Immobilization of Nanoparticles on Fibrous Clay Surfaces: Towards Promising Nanoplatforms for Advanced Functional Applications

Aranda Pilar; Ruiz‐Hitzky Eduardo

摘要

Abstract > This account discusses on diverse general approaches employed for the preparation of heterostructured materials based on the immobilization of metal oxides and other nanoparticles on sepiolite and palygorskite fibrous clay minerals, showing the many opportunities of application offered by the resulting materials. Various examples from our own experience have been selected to show how sepiolite acts as a convenient nanoplatform for immobilization of diverse type of nanoparticles, such as TiO <sub>2</sub> , Fe <sub>3</sub> O <sub>4</sub> , Prussian blue, zeolites, layered double hydroxides, carbon nanotubes and graphenes, etc., to produce functional materials for applications in catalysis, environmental remediation, sensing devices, energy production, and others. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >本账户讨论了用于根据固定化制备异质结构材料的不同一般方法金属氧化物和海硫醇盐和甲晶纤维粘土矿物质的其他纳米颗粒，显示由所得材料提供的诸多应用的机会。从我们自己的经验中选择了各种实例，展示了Sepiolite如何作为一种方便的纳米薄纱，用于固定各种类型的纳米颗粒，例如TiO <Sub> 2 </ sub>，Fe <Sub> 3 </ sub> O <sub > 4 </ sub>，普鲁士蓝，沸石，层状双氢氧化物，碳纳米管和石墨烯等，为催化作用，环境修复，传感装置，能源生产等生产功能材料。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16132/'>《Chemical record》</a> <b style="margin: 0 2px;">|</b><span>2018年第8期</span><b style="margin: 0 2px;">|</b><span>共13页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Aranda Pilar&option=202" target="_blank" rel="nofollow">Aranda Pilar;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ruiz‐Hitzky Eduardo&option=202" target="_blank" rel="nofollow">Ruiz‐Hitzky Eduardo;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Instituto de Ciencia de Materiales de MadridCSICc/ Sor Juana Inés de la Cruz 3 28049 Madrid Spain;</p> <p>Instituto de Ciencia de Materiales de MadridCSICc/ Sor Juana Inés de la Cruz 3 28049 Madrid Spain;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/159.html" title="化学">化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=sepiolite&option=203" rel="nofollow">sepiolite;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=palygorskite&option=203" rel="nofollow">palygorskite;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nanoparticles&option=203" rel="nofollow">nanoparticles;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nanoarchitectures&option=203" rel="nofollow">nanoarchitectures;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=functional materials&option=203" rel="nofollow">functional materials;</a> </p> <div class="translation"> 机译：海泡石;帕莱戈斯斯基岩;纳米粒子;纳米建筑;功能材料; 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href="/academic-degree-domestic_mphd_thesis/02031629440.html">NiCoP纳米片在水系纤维状储能器件中的应用</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=谢丽艳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 谢丽艳</a> <span> . 2019</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061203632345.html">一种多孔高比表面积的铋纳米颗粒修饰的氮掺杂碳纳米片材料及其制备方法和应用</a> <b>[P]</b> . <span> 中国专利： CN107824797B </span> <span> . 2020.02.11</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120110305400.html">一种多孔高比表面积的铋纳米颗粒修饰的氮掺杂碳纳米片材料及其制备方法和应用</a> <b>[P]</b> . <span> 中国专利： CN107824797A </span> <span> . 2018-03-23</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130499938559.html">EFFICIENT LIGAND EXCHANGE OF A DETERGENT BILAYER ON THE SURFACE OF METAL NANOPARTICLES FOR MOLECULAR FUNCTIONALIZATION AND ASSEMBLY, CORRESPONDING FUNCTIONALIZED NANOPARTICLES AND NANOPARTICLE ASSEMBLIES, AND THEIR USE IN PLASMONIC APPLICATIONS INCLUDING SURFACE-ENHANCED RAMAN SPECTROSCOPY</a> <b>[P]</b> . <span> 外国专利：  US2021140953A1 </span> <span> . 2021-05-13</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于分子官能化和组装的金属纳米颗粒表面上的洗涤剂双层的高效配体交换，相应的官能化纳米颗粒和纳米颗粒组件，以及它们在具有表面增强拉曼光谱的等离子体应用中的应用 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130402640498.html">EFFICIENT LIGAND EXCHANGE OF A DETERGENT BILAYER ON THE SURFACE OF METAL NANOPARTICLES FOR MOLECULAR FUNCTIONALIZATION AND ASSEMBLY, CORRESPONDING FUNCTIONALIZED NANOPARTICLES AND NANOPARTICLE ASSEMBLIES, AND THEIR USE IN PLASMONIC APPLICATIONS INCLUDING SURFACE-ENHANCED RAMAN SPECTROSCOPY</a> <b>[P]</b> . <span> 外国专利：  EP3593137A1 </span> <span> . 2020-01-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：分子功能和组装用金属纳米粒子表面上有效二元交换剂的有效配体交换，相应的功能化纳米粒子和纳米粒子组装及其在等离子应用中的使用（包括表面粗糙度） </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130406153884.html">EFFICIENT LIGAND EXCHANGE OF A DETERGENT BILAYER ON THE SURFACE OF METAL NANOPARTICLES FOR MOLECULAR FUNCTIONALIZATION AND ASSEMBLY, CORRESPONDING FUNCTIONALIZED NANOPARTICLES AND NANOPARTICLE ASSEMBLIES, AND THEIR USE IN PLASMONIC APPLICATIONS INCLUDING SURFACE-ENHANCED RAMAN SPECTROSCOPY</a> <b>[P]</b> . <span> 外国专利：  WO2018162742A1 </span> <span> . 2018-09-13</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：分子功能和组装用金属纳米粒子表面上有效二元交换剂的有效配体交换，相应的功能化纳米粒子和纳米粒子组装及其在等离子应用中的使用（包括表面粗糙度） </span> </p> </li> </ul> </div> </div> </div> <div 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