Model-Based Design of Experiments for Kinetic Study of Anisole Upgrading Process over Pt/γAl2O3: Model Development and Optimization by Application of Response Surface Methodology and Artificial Neural Network

摘要

The kinetic of catalytic upgrading of anisole as a ligninderived biooil component is investigated experimentally over Pt/γAl2O3 at 573673 K and 14 bar. According to experimental results, benzene, phenol, 2methylphenol, 2,6dimethylphenol, 2,4,6trimethylphenol, and hexamethylbenzene are identified as the main products. The results indicated that the kinetically significant reaction classes are hydrogenolysis, hydrodeoxygenation (HDO), alkylation, and hydrogenation. The response surface methodology (RSM) is applied to optimize the experimental data which obtained at suggested conditions by design of experiment (DOE). Due to the complex nature of the system, artificial neural networks (ANNs) were employed as an efficient tool to model the behavior of the system. RSM and ANN methods were constructed based upon the DOE’s points and then utilized for generating extrasimulated data. Data simulated by the RSM/ANN method were used to fit power law kinetic rate expressions for the reactions. The coefficient of determination (R2) was obtained 0.998 and 0.973 for anisole conversion model and benzene selectivity model which represented the high accuracy of model predictions. The correlation coefficient (R) and mean square error (MSE) of ANN model equaled to 0.97 and 8.3 × 1012 respectively means high accuracy of the developed model. The results of kinetic modeling with simulated data from the ANN and RSM models revealed that the highest reaction order during the upgrading process of anisole belongs to hydrogenolysis of anisole to phenol. Also the activation energy of hydrogenolysis reaction was lower than HDO.