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Hydrodeoxygenation of Fatty Acids, Triglycerides, and Ketones to Liquid Alkanes by a Pt–MoO x xx /TiO 22 Catalyst

机译:通过PT-Moo将脂肪酸,甘油三酯和酮与液体烷烃加氢脱氧氧基 x x x / TiO. 2 2 催化剂

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Abstract > Various supported metal catalysts are screened for hydrogenation of lauric acid and 2‐octanone as model reactions for the transformation of biomass‐derived oxygenates to liquid alkanes (biofuels) in a batch reactor under solvent‐free conditions. Among the catalysts tested, Pt and MoO <sub> x </sub> co‐loaded on TiO <sub>2</sub> (Pt–MoO <sub> x </sub> /TiO <sub>2</sub> ) shows the highest yields of n ‐alkanes for both of the reactions. Pt–MoO <sub> x </sub> /TiO <sub>2</sub> selectively catalyzes the hydrodeoxygenation of various fatty acids and triglycerides to n ‐alkanes without C?C bond cleavage under 50?bar H <sub>2</sub> and shows higher turnover numbers than the catalysts in the literature. Pt–MoO <sub> x </sub> /TiO <sub>2</sub> is effective also for the hydrodeoxygenation of various ketones to the corresponding alkanes. In situ IR study of the reaction of adsorbed acetone under H <sub>2</sub> suggests that the high activity of Pt–MoO <sub> x </sub> /TiO <sub>2</sub> is attributed to the cooperation between Pt and Lewis acid sites of the MoO <sub> x </sub> /TiO <sub>2</sub> support. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract Type =“Main”XML:Lang =“en”> <标题类型=“main”>抽象</ title> > 筛选各种负载的金属催化剂,用于氢化月桂酸和2-辛烷酮作为模型反应,以在无溶剂条件下在批量反应器中转化生物质衍生的含氧化合物(生物燃料)。在测试的催化剂中,PT和MOO <sub> x </ i> </ sub> 加入TiO <sub> 2 </ sub> (PT-Moo <sub> x </ i> </ sub> / TiO. <sub> 2 </ sub> )显示最高产量 n </ i> - 两种反应的alkanes。 Pt-moo <sub> x </ i> </ sub> / TiO. <sub> 2 </ sub> 选择性地催化各种脂肪酸和甘油三酯的加氢脱氧酶 n </ i> - alkanes没有c?c键裂解50岁以下的裂解 <sub> 2 </ sub> 并且显示出比文献中的催化剂更高的营业额数。 Pt-moo <sub> x </ i> </ sub> / TiO. <sub> 2 </ sub> 也有效地用于各种酮的加氢脱氧到相应的烷烃。原位IR研究了H下吸附丙酮的反应 <sub> 2 </ sub> 表明pt-moo的高活动 <sub> x </ i> </ sub> / TiO. <sub> 2 </ sub> 归因于MOO的PT和Lewis酸遗址之间的合作 <sub> x </ i> </ sub> / TiO. <sub> 2 </ sub> 支持。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16041/'>《ChemCatChem》</a> <b style="margin: 0 2px;">|</b><span>2017年第14期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学(理论化学)、化学物理学">物理化学(理论化学)、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=fatty acids&option=203" rel="nofollow">fatty acids;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hydrodeoxygenation&option=203" rel="nofollow">hydrodeoxygenation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ketones&option=203" rel="nofollow">ketones;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=platinum&option=203" rel="nofollow">platinum;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=triglycerides&option=203" rel="nofollow">triglycerides;</a> </p> <div class="translation"> 机译:脂肪酸;加氢脱氧;酮;铂;甘油三酯; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022060097.html">Hydrodeoxygenation of Fatty Acids, Triglycerides, and Ketones to Liquid Alkanes by a Pt–MoO <sub > x </sub> <i >xx /TiO <sub >2</sub>2 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=商江伟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 商江伟</a> <span> . 2019</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120103741131.html">一种脂肪酸甲酯加氢脱氧制备烷烃的催化剂及制备方法和用途</a> <b>[P]</b> . <span> 中国专利: CN111250123A </span> <span> . 2020-06-09</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120103738191.html">一种脂肪酸甲酯加氢脱氧-异构制备烷烃的催化剂及制备方法和用途</a> <b>[P]</b> . <span> 中国专利: CN111250156A </span> <span> . 2020-06-09</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130427913599.html">Methods for producing triglycerides rich in XX or XX fats include heating and dissolving 20-60 of triglycerides (XX or XX) containing 1.3 position saturated fatty acid residues, 2 positions of oils and/or linoleic groups, and 1-30 of fatty acid esters. Cooling, separation.</a> <b>[P]</b> . <span> 外国专利: <!-- --> CL2008003889A1 </span> <span> . 2010-03-12</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:生产富含XX或XX脂肪的甘油三酸酯的方法包括加热和溶解20-60%的甘油三酸酯(XX或XX),其中甘油三酸酯包含1.3个位置的饱和脂肪酸残基,2个位置的油和/或亚油基以及1-30%的脂肪酸酯。冷却,分离。 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130429361014.html">Catalyst, process for preparing the (OPTIONS) AND METHOD hydrodeoxygenation fatty acid esters and triglycerides</a> <b>[P]</b> . <span> 外国专利: <!-- 俄罗斯专利: --> RU2007131911A </span> <span> . 2009-02-27</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:催化剂,制备方法(方法)和方法加氢脱氧脂肪酸酯和甘油三酸酯 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130429326575.html">CATALYST, METHOD OF MAKING IT (VERSIONS) AND METHOD OF HYDRODEOXYGENATION OF FATTY ACIDS, THEIR ESTERS AND TRIGLYCERIDES</a> <b>[P]</b> . <span> 外国专利: <!-- 俄罗斯专利: --> RU2356629C1 </span> <span> . 2009-05-27</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:脂肪酸,其酯和甘油的催化剂,制备方法(版本)和加氢氧合方法 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704022060097','4',7,2,1,'',this,24)" class="delivery" prompt="010401" 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