A trifluoromethyl substituted wide bandgap conjugated polymer for non-fullerene polymer solar cells with 10.4% efficiency

摘要

A new wide bandgap copolymer (PBZ-m-CF3) based on meta-trifluoromethyl-p-alkoxyphenyl substituted benzodithiophene (BDTP-m-CF3) and difluorobenzotriazole (FBTZ) was successfully designed and synthesized for efficient non-fullerene polymer solar cells (PSCs). As a comparative material, a wide bandgap copolymer (PBZ1) based on p-alkoxyphenyl substituted benzodithiophene (BDTP) and FBTZ was synthesized by the same method. It was found that introducing trifluoromethyl into the metaposition of the phenyl group led to PBZ-m-CF3 possessing a deeper HOMO energy level of -5.49 eV, a wider optical bandgap (E-g(opt)) of 1.99 eV with a higher extinction coefficient of 6.51 x 10(4) cm(-1) at 533 nm and a suitable hole mobility of 7.86 x 10(-4) cm(2) V-1 s(-1) in comparison with PBZ1 (a HOMO level of -5.27 eV, an E-g(opt) of 1.96 eV with an extinction coefficient of 5.23 x 10(4) cm(-1) at 539 nm and a hole mobility of 7.23 x 10(-4) cm(2) V-1 s(-1)). Non-fullerene bulk heterojunction PSCs based on PBZ-m-CF3 as the donor and ITIC as the acceptor were fabricated by using toluene as the solvent and showed a higher PCE of 10.4% with a high V-oc of 0.94 V, a J(sc) of 18.4 mA cm(-2), and a FF of 60.2% compared with PSCs based on PBZ1: ITIC (a PCE of 5.8% with a V-oc of 0.74 V, a J(sc) of 15.7 mA cm(-2), and a FF of 49.8%). These results demonstrate that a benzodithiophene unit with meta-trifluoromethyl-p-alkoxyphenyl side chains is a promising candidate as an electron-rich building block for high performance PSCs.