Kinetics and Mechanism of Oxidation of Paracetamol by Thallic Perchlorate in Acid Medium

Deepmala Pareek; Riya Sailani; Vinita K. Gupta; Chandra L. Khandelwal; Prem D. Sharma

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Kinetics and Mechanism of Oxidation of Paracetamol by Thallic Perchlorate in Acid Medium

机译：酸性介质中邻苯二甲酸高氯酸盐氧化扑热息痛的动力学及机理

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The kinetics and mechanism of oxidation of paracetamol (PCM) by thallium (III) in acid perchlorate medium has been studied. The reaction exhibits first order kinetics with respect to the oxidant but a complex dependence of the substrate. The rate is reduced by an increase in the hydrogen ion concentration in a complex manner. A plausible reaction mechanism has been suggested to account for experimental observations.

机译：研究了在高氯酸酸介质中（（III）氧化扑热息痛（PCM）的动力学和机理。该反应相对于氧化剂表现出一级动力学，但是对底物具有复杂的依赖性。通过以复杂的方式增加氢离子浓度来降低该速率。已经提出了合理的反应机理来解释实验观察。

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《Current Physical Chemistry》 |2014年第3期|共8页
作者
Deepmala Pareek; Riya Sailani; Vinita K. Gupta; Chandra L. Khandelwal; Prem D. Sharma;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Kinetics; mechanism; oxidation; paracetamol; thallic perchlorate;

机译：动力学机理氧化对乙酰氨基酚邻苯二甲酸高氯酸盐;

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1. Kinetics and Mechanism of Oxidation of Paracetamol by Thallic Perchlorate in Acid Medium [J] . Deepmala Pareek, Riya Sailani, Vinita K. Gupta, Current Physical Chemistry . 2014,第3期

机译：酸性介质中邻苯二甲酸高氯酸盐氧化扑热息痛的动力学及机理
2. Kinetics and mechanism of electron transfer reactions: Oxidation of glyoxylic acid by peroxomonophosphoric acid in acid perchlorate medium [J] . N Vijai, D Mala, C L Khandelwal Indian Journal of Chemistry, Section A. Inorganic, Physical, Theoretical & Analytical . 2008,第6期

机译：电子转移反应的动力学和机制：酸性氯酸盐磷酸中过氧磷酸的氧化氧化酸氧化
3. Kinetics and mechanism of oxidation of paracetamol by an Anderson-type 6-molybdocobaltate(III) in acidic medium [J] . Sawant Jyoti D., Patil Kranti K., Gokavi Gavisiddappa S. Transition Metal Chemistry . 2019,第2期

机译：Anderson-型6-钼酰基（III）在酸性介质中的扑热氨基酚氧化动力学和机理
4. Fluorescence Enhancement of Europium(III) Perchlorate by Salicylic Acid on Phenyl-naphthoylmethyl Sulfoxide Complex and Luminescence Mechanism [C] . Wen Xian Li, Jing Zhang, Bo Yang Ao, International Conference on Chemical, Material and Metallurgical Engineering . 2013

机译：通过水杨酸对苯基 - 萘甲基亚甲基亚甲基亚甲基络合物和发光机制的荧光增强（III）高氯酸盐
5. Oxidation of Aromatic Amino Acids by Ferrate(VI): Kinetics and Mechanisms. [D] . Casbeer, Erik Michael. 2012

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6. Oxidation of crotyl alcohol by N-chloro-4-methylbenzene sulphonamide in acidic medium and in alkaline media in the presence of os(VIII) catalyst-a kinetic pathway [O] . Priyamvada SHARMA, Riya SAILANI, Anita MEENA, 2020

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7. Kinetics and mechanisms of oxidation of d-fructose and d-lactose by permanganate ion in acidic medium [O] . Imran Malik, Noshab Qamar, Raheela Naz, 2012

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Kinetics and Mechanism of Oxidation of Paracetamol by Thallic Perchlorate in Acid Medium

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