Phosphinoyl Radical Initiated Vicinal Cyanophosphinoylation of Alkenes

Zhang Pei-Zhi; Zhang Ling; Li Jian-An; Shoberu Adedamola; Zou Jian-Ping; Zhang Wei

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Phosphinoyl Radical Initiated Vicinal Cyanophosphinoylation of Alkenes

机译：磷酰基激发引发烯烃的邻苯甲酸亚磷酰基

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A double-functionalization reaction of alkenes through Mn-(OAc)(3)-mediated phosphinoyl radical addition followed by CuCN-catalyzed cyanation is introduced. This one-pot reaction is performed under mild conditions to afford vicinal cyanophosphinoylation products.

机译：烷烃通过Mn-（OAC）（3）介导的磷酰基自由基加成，然后用CUCN催化的染色剂进行双官能化反应。该单壶反应在温和的条件下进行，得到维护氰基磷酸盐产物。

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《Organic letters》 |2017年第20期|共4页
作者
Zhang Pei-Zhi; Zhang Ling; Li Jian-An; Shoberu Adedamola; Zou Jian-Ping; Zhang Wei;
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作者单位

Soochow Univ Key Lab Organ Synth Jiangsu Prov Coll Chem &

Chem Engn Suzhou 215123 Jiangsu Peoples R China;

Soochow Univ Key Lab Organ Synth Jiangsu Prov Coll Chem &

Chem Engn Suzhou 215123 Jiangsu Peoples R China;

Soochow Univ Key Lab Organ Synth Jiangsu Prov Coll Chem &

Chem Engn Suzhou 215123 Jiangsu Peoples R China;

Soochow Univ Key Lab Organ Synth Jiangsu Prov Coll Chem &

Chem Engn Suzhou 215123 Jiangsu Peoples R China;

Soochow Univ Key Lab Organ Synth Jiangsu Prov Coll Chem &

Chem Engn Suzhou 215123 Jiangsu Peoples R China;

Univ Massachusetts Dept Chem Boston MA 02125 USA;

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正文语种 eng
中图分类有机化学;
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1. Phosphinoyl Radical Initiated Vicinal Cyanophosphinoylation of Alkenes [J] . Zhang Pei-Zhi, Zhang Ling, Li Jian-An, Organic letters . 2017,第20期

机译：磷酰基激发引发烯烃的邻苯甲酸亚磷酰基
2. Phosphinoyl Radical-Initiated 1,2-Bifunctional Thiocyanodiphenylphosphinoylation of Alkenes [J] . Ze-Kun Tao, Cheng-Kun Li, Pei-Zhi Zhang, The Journal of Organic Chemistry . 2018,第4期

机译：磷酰基自由基引发的1,2-双官能硫氰酸噻吩基膦酰基磷酸烯烃
3. Phosphinoyl Radical-Initiated alpha,beta-Aminophosphinoylation of Alkenes [J] . Li Jian-An, Zhang Pei-Zhi, Liu Kui, Organic letters . 2017,第17期

机译：磷酰基激发α，β-氨基磷酰基烯烃
4. MODELING OF REVERSE ATOM TRANSFER RADICAL POLYMERIZATION IN MINIEMULSION INITIATED BY A WATER-SOLUBLE RADICAL INITIATOR [C] . Ayelen Zurman, Mariano Asteasuain, Claudia Sarmoria AIChE Annual Meeting . 2016

机译：水溶性自由基引发剂引发逆原子转移自由基聚合的建模
5. Secondary organic aerosol formation from radical-initiated reactions of alkenes: Development of mechanisms [D] . Matsunaga, Aiko 2009

机译：烯烃自由基引发的二次有机气溶胶形成：机理发展
6. Vicinal difunctionalization of alkenes by four-component radical cascade reaction of xanthogenates alkenes CO and sulfonyl oxime ethers [O] . Shuhei Sumino, Takahide Fukuyama, Mika Sasano, 2019

机译：黄原酸酯烯烃CO和磺酰基肟醚的四组分自由基级联反应使烯烃的双官能化
7. Phosphinoyl Radical-Initiated ,-Aminophosphinoylation of Alkenes [O] . -1

机译：磷酰基激发 - 启动， - 烯烃磷酸烯烃
8. Photochemistry of Alkenes. IV. Vicinally Unsymmetrical Olefins in Hydroxylic Media. [R] . Fravel, H. G., Kropp, P. J. 1975

机译：烯烃的光化学。 IV。羟基介质中的邻近不对称烯烃。

Phosphinoyl Radical Initiated Vicinal Cyanophosphinoylation of Alkenes

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