Electrochemical Removal of Radioactive Cesium from Nuclear Waste Using the Dendritic Copper Hexacyanoferrate/Carbon Nanotube Hybrids

摘要

Highlights?Copper hexacyanoferrate was uniformly covered on carbon nanotubes.?Cs+ion can be exchanged using this hybrid by controlling the electrode potential.?The maximum of Cs+adsorption capacity is 310 mg·g?1in 50μM Cs+solution.?The distribution coefficient of Cs+in this hybrid reaches up to 568 L·g?1,.?This hybrid can be regenerated with high stability for Cs+exchange.AbstractA novel electrochemical separation system was developed based on copper hexacyanoferrate/multiwalled carbon nanotube (CuHCF/MWCNT) hybrids for selectively removing cesium from wastewater. These CuHCF/MWCNT hybrids were prepared by co-precipitation strategy. The as-prepared CuHCF nanoparticles were uniformly covered on MWCNTs to form a dendritic core-shell structure. This novel structure can improve CuHCFs conductivity, making CuHCFs more accessible for ion exchange. The uptake and release of alkali ion in CuHCF/MWCNT hybrids can be shifted mutually by switching the applied potentials between the anode and cathode. This ion exchange is a fast and reversible process associated with electron transfer in CuHCFs. The potential response depends on the radius of alkali ion. Using this electrochemical adsorption system (EAS), the maximum adsorption capacity (Qmax) of Cs+ion for CuHCFs/MWCNT hybrids reaches up to 310 mg·g?1in 50μM Cs+solution with a distribution coefficient Kdof 568 L·g?1, superior to the Cs+removal performance by the conventional adsorption system (Qmax230 mg·g?1, Kd 389 L·g?1). Besides, CuHCF/MWCNT hybrids can be regenerated electrochemically. In addition to the advantages in Cs+removal performance and electrochemical regenerability, they can maintain considerable stability with uptake capacity retention of 85% after 100 cycles of adsorption and regeneration.]]>