Synthesis, thermochromic, solvatochromic and axial ligation studies of Zn-porphyrin complex

Jaemyeng Jeong; Rangaraju Satish Kumar; Mergu Naveen; Young-A Son

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Synthesis, thermochromic, solvatochromic and axial ligation studies of Zn-porphyrin complex

机译：Zn-卟啉复合物的合成，热致致变色，溶性溶质和轴连接研究

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?In the present study, porphyrin dye was synthesized and fully characterized.

?The thermochromic, solvatochromic and sensing properties of the dye were evaluated by UV–Vis and emission studies.

?DFT calculations were conducted to rationalize the dye structure.

?The thermochromic property of this compound was studied in toluene, different temperature variations.

?This is the first attempt of a study of solvatochromism and axial coordination studies of pyridyl-porphyrin monomers.

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机译：<！[cdata [

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< CE：简单段ID =“SP0010”View =“全部”>

？在本研究中，合成和完全表征卟啉染料。

？ D的热致变色，溶色素质和传感属性YE是通过UV-VIS和排放研究评估的。

？ < CE：PARA ID =“P0015”查看=“全部”>进行DFT计算以合理化染料结构。

？在甲苯中研究该化合物的热致变色性质，不同的温度变化。

？这是第一次尝试吡啶基卟啉单体溶血剂和轴向协调研究的研究。

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来源
《Inorganica Chimica Acta》 |2018年第2018期|共8页
作者
Jaemyeng Jeong; Rangaraju Satish Kumar; Mergu Naveen; Young-A Son;
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作者单位

Department of Advanced Organic Materials Engineering Chungnam National University;

Department of Advanced Organic Materials Engineering Chungnam National University;

Department of Advanced Organic Materials Engineering Chungnam National University;

Department of Advanced Organic Materials Engineering Chungnam National University;

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正文语种 eng
中图分类无机化学;
关键词
Thermochromic; Solvatochromism; Pyridyl; Porphyrin; CNU-TJK;

机译：Thermochromic;Solvatochromism;吡啶基;卟啉;CNU-TJK;

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1. Synthesis, thermochromic, solvatochromic and axial ligation studies of Zn-porphyrin complex [J] . Jaemyeng Jeong, Rangaraju Satish Kumar, Mergu Naveen, Inorganica Chimica Acta . 2018,第期

机译：Zn-卟啉复合物的合成，热致致变色，溶性溶质和轴连接研究
2. Synthesis and structural, photophysical, electrochemical redox and axial ligation properties of highly electron deficient perchlorometalloporphyrins and selective CN- sensing by Co(II) complexes [J] . Chaudhri Nivedita, Butcher Ray J., Sankar Muniappan New Journal of Chemistry . 2018,第10期

机译：高电子缺陷型Herchloromophoporlins的合成和结构，光学，电化学氧化还原及轴连接性能，CO（II）复合物选择性CN-感测
3. SYNTHESIS AND CRYSTALLOGRAPHIC CHARACTERIZATION OF MANGANESE(III) SCHIFF BASE COMPLEXES WITH AXIAL CARBOXYLATE LIGATION [J] . H. Roseben, K. Sreebala, V. S. Thampidas European Chemical Bulletin . 2014,第7期

机译：轴向羧酸盐键合锰（III）席夫夫碱配合物的合成及晶体学表征
4. Thermochromic and solvatochromic properties of CoCl{sub}2 solution [C] . Wojciech Wroblewski, Anna Strzelczyk, Artur Dybko Conference on optoelectronic and electronic sensors . 2001

机译：COCL {SUB} 2溶液的热致变色和溶性溶剂变色性能
5. Probing the interactions between sterically demanding ferrihemes and histidine analogues. I. 2-D NMR studies of nonplanar ferriheme/bis(N-/2-methylimidazole) complexes; II. Synthesis of a trans-disubstituted tetraarylporphyrin with a bulky group near each potential axial ligation site. [D] . Ogura, Hiroshi. 2000

机译：探索空间需求的亚铁和组氨酸类似物之间的相互作用。 I.非平面亚铁血红素/双（N- / 2-甲基咪唑）配合物的2-D NMR研究；二。在每个潜在的轴向连接位点附近具有大体积基团的反式二取代四芳基卟啉的合成。
6. Biosynthesis of organic photosensitizer Zn-porphyrin by diphtheria toxin repressor (DtxR)-mediated global upregulation of engineered heme biosynthesis pathway in Corynebacterium glutamicum [O] . Young Jin Ko, Young-Chul Joo, Jeong Eun Hyeon, -1

机译：白喉毒素阻遏物（DtxR）介导的谷氨酸棒状杆菌血红素生物合成途径的整体上调生物合成有机光敏剂锌卟啉
7. Probing the interactions between sterically demanding ferrihemes and histidine analogues. I. 2-D NMR studies of nonplanar ferriheme/bis(N-/2-methylimidazole) complexes; II. Synthesis of a trans-disubstituted tetraarylporphyrin with a bulky group near each potential axial ligation site [O] . Ogura Hiroshi 2000

机译：探索空间需求的亚铁和组氨酸类似物之间的相互作用。 I.非平面亚铁血红素/双（N- / 2-甲基咪唑）配合物的2-D NMR研究；二。在每个潜在的轴向连接位点附近具有大体积基团的反式二取代四芳基卟啉的合成
8. Synthesis of Thermochromic Dibismuthines with Non-Thermochromic Distibine Analogs. [R] . Spence, R. E., Hsu, D. P., Davis, W. M., 1992

机译：用热致变色的去纤维素类似物合成热致变色二嗪。

Synthesis, thermochromic, solvatochromic and axial ligation studies of Zn-porphyrin complex

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