Hydrolysis of-N=CH-Bond in 2-SalicyIidene-4-aminophenyI benzimidazole by Palladium(II)

M.Chandrakala

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Hydrolysis of-N=CH-Bond in 2-SalicyIidene-4-aminophenyI benzimidazole by Palladium(II)

机译：钯（II）的2- salicyiidene-4-氨基苯甲唑苯并咪唑水解-N = Ch-键水解

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The Schiff base,2-salicylidene-4-aminophenyl benzimidazole(I,SAPbzlH)in ethanolic medium reacts with palladium(II)in acidic medium(HCl/HBr)and coordinated SAPbzlH undergoes hydrolysis at-N=CH-bond to yield salicylaldehyde and square planar complexes having composition [Pd(C_(13)H_(11)N3)2X2]·2HX(II)(X = Cl,Br).The obtained complexes have been characterized by elemental analysis,atomic absorption spectra,infrared,electronic and extensive utility of NMR.Possible mechanism for the hydrolysis of coordinated 2-salicylidene-4-aminophenyl benzimidazole(SAPbzlH)has been proposed.

机译：乙醇介质中的辛磷基碱，2-水杨基-4-氨基苯基苯并咪唑（I，SAPBZLH）与酸性介质（HCl / HBr）中的钯（II）反应，并协调Sapbzlh在-N = Ch-键处进行水解，得到水杨醛和具有组合物的方形平面络合物[Pd（C_（13）H_（11）N 3）2×2]·2HX（II）（X = Cl，BR）。所得复合物的特征在于元素分析，原子吸收光谱，红外线，电子并提出了NMR的良好效用。已经提出了对配位的2-水杨基-4-氨基苯基苯并咪唑（SAPBZLH）水解的涂布机制。

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来源
《Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry》 |2019年第2期|共6页
作者
M.Chandrakala;
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作者单位

Department of Chemistry Bangalore Institute of Technology Bengaluru-560004 India;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Schiff base; Divalent palladium; Correlation spectroscopy; Hydrolysis;

机译：Schiff Base;二价钯;相关光谱;水解;

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1. Hydrolysis of-N=CH-Bond in 2-SalicyIidene-4-aminophenyI benzimidazole by Palladium(II) [J] . M.Chandrakala Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry . 2019,第2期

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Hydrolysis of-N=CH-Bond in 2-SalicyIidene-4-aminophenyI benzimidazole by Palladium(II)

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