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A novel Au-Pt@PPy(polypyrrole) coral-like structure: Facile synthesis, high SERS effect, and good electro catalytic activity

机译:一种新颖的Au-Pt @ PPy(聚吡咯)珊瑚状结构:合成简便,SERS效果好,电催化活性好

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摘要

The Au-Pt@PPy(polypyrrole) with a novel three-dimensional structure was synthesized by a facile one-pot reaction. Raman spectra, transmission electron microscopy (TEM), scanning electron microscopy (SEM), UV-vis spectroscopy (UV-vis), and cyclic voltammograms (CV) were employed to characterize the complex. TEM and SEM results indicated that the products had novel three-dimensional (3D) multi-branch structures, which were controllable by simply adjusting the ratios of HAuCl_4 to H_2PtCl_6 added. Raman characterization proved that the products had significant surface-enhanced Raman effect with the aid of long-range effect of the enhanced electromagnetic (EM) field and roughness in nanometer-scale. CV results showed that the Au-Pt@PPy with coral-like structure had high catalytic efficiency for methanol oxidation.
机译:通过简单的一锅反应合成了具有新型三维结构的Au-Pt @ PPy(聚吡咯)。拉曼光谱,透射电子显微镜(TEM),扫描电子显微镜(SEM),紫外-可见光谱(UV-vis)和循环伏安图(CV)用于表征该配合物。 TEM和SEM结果表明,该产品具有新颖的三维(3D)多分支结构,可通过简单地调节HAuCl_4与H_2PtCl_6的比例来控制。拉曼表征证明,借助于增强的电磁场和纳米级粗糙度的远距离影响,产品具有显着的表面增强拉曼效应。 CV结果表明,具有珊瑚状结构的Au-Pt @ PPy具有较高的甲醇氧化催化效率。

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