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首页> 外文期刊>The Journal of Chemical Physics >Asymptotic neutron scattering laws for anomalously diffusing quantum particles
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Asymptotic neutron scattering laws for anomalously diffusing quantum particles

机译:量子粒子异常扩散的渐近中子散射定律

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The paper deals with a model-free approach to the analysis of quasielastic neutron scattering intensities from anomalously diffusing quantum particles. All quantities are inferred from the asymptotic form of their time-dependent mean square displacements which grow proportional to t(alpha), with 0 <= alpha < 2. Confined diffusion (alpha = 0) is here explicitly included. We discuss in particular the intermediate scattering function for long times and the Fourier spectrum of the velocity autocorrelation function for small frequencies. Quantum effects enter in both cases through the general symmetry properties of quantum time correlation functions. It is shown that the fractional diffusion constant can be expressed by a Green-Kubo type relation involving the real part of the velocity autocorrelation function. The theory is exact in the diffusive regime and at moderate momentum transfers. Published by AIP Publishing.
机译:该论文采用了一种无模型的方法来分析来自异常扩散量子粒子的准弹性中子散射强度。从与时间成正比的均方位移的渐近形式可以推断出所有数量,这些均方根位移与t(alpha)成正比,其中0 <= alpha <2。这里明确包括了受限扩散(alpha = 0)。我们将特别讨论长时间的中间散射函数和小频率的速度自相关函数的傅立叶谱。在两种情况下,量子效应都是通过量子时间相关函数的一般对称性进入的。结果表明,分数扩散常数可以由涉及速度自相关函数实部的格林库伯型关系表示。该理论在扩散状态和适度的动量传递中是精确的。由AIP Publishing发布。

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