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首页> 外文期刊>The Journal of Chemical Physics >Remote detection of hyperpolarized Xe-129 resonances via multiple distant dipolar field interactions with H-1
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Remote detection of hyperpolarized Xe-129 resonances via multiple distant dipolar field interactions with H-1

机译:通过与H-1的多个远距离偶极场相互作用远程检测超极化Xe-129共振

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摘要

A remote detection scheme utilizing the distant dipolar field interaction between two different spin species was proposed by Granwehr et al. [J. Magn. Reson. 176(2), 125 (2005)]. In that sequence H-1 spins were detected indirectly via their dipolar field interaction with Xe-129 spins, which served as the sensing spins. Here we propose a modification of the proposed detection scheme that takes advantage of the longer T-1 relaxation time of xenon to create a long lasting dipolar field with which the fast relaxing H-1 spins are allowed to interact many times during a single acquisition. This new acquisition scheme improves detection sensitivity, but it also presents some challenges. Published by AIP Publishing.
机译:Granwehr等人提出了利用两种不同自旋物种之间遥远的偶极场相互作用的远程检测方案。 [J.真是的雷森176(2),125(2005)]。在该序列中,H-1自旋通过与Xe-129自旋的偶极场相互作用而间接检测到,Xe-129自旋用作传感自旋。在这里,我们提出了一种对所提议的检测方案的改进,该方案利用了氙气的更长的T-1弛豫时间来创建一个持久的偶极场,在一次采集过程中,快速弛豫H-1自旋被允许与之相互作用多次。这种新的采集方案提高了检测灵敏度,但同时也带来了一些挑战。由AIP Publishing发布。

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