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首页> 外文期刊>The Journal of Chemical Physics >The study of the structure factor of a wormlike chain in an orientational external field
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The study of the structure factor of a wormlike chain in an orientational external field

机译:定向外场中蠕虫状链结构因素的研究

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A precise representation of the structure factor of a wormlike chain for the arbitrary chain flexibility in an orientational external field is obtained by virtue of the numerical solution to the modified diffusion equation satisfied by the Green's function. The model is built from a standard wormlike chain formalism in a continuous version which crossovers from the rigid-rod limit to the flexible chain limit and the Maier-Saupe interaction which describes the orientational effects from the nematic field. The behaviors of the structure factor in the distinct wavevector k regimes are numerically investigated as functions of chain flexibility and tilt angle between the directors of the nematic field and k. The radius of gyration extracted from the structure factor in small-k regime is also carefully analysed in both the directions along and perpendicular to the nematic axis. Our calculations exactly recover the prediction of the structure factor undergoing an orientational field in the rigid rod limit. (C) 2015 AIP Publishing LLC.
机译:借助于格林函数满足的修正扩散方程的数值解,可以得到定向外场中任意链柔性的蠕虫状链结构因子的精确表示。该模型从标准的蠕虫状链形式主义以连续版本构建而成,该形式从刚性杆极限到柔性链极限以及Maier-Saupe相互作用进行交叉,描述了向列域的定向效应。数值研究了不同波矢k体制下结构因子的行为,作为向列场和k的指向矢之间链柔性和倾斜角的函数。从小k态的结构因子中提取的回转半径也在沿向列轴和垂直于向列轴的方向上进行了仔细分析。我们的计算精确地恢复了在刚性杆极限内经历定向场的结构因子的预测。 (C)2015 AIP Publishing LLC。

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