...
首页> 外文期刊>The Journal of Chemical Physics >Three hard spheres in a spherical cavity
【24h】

Three hard spheres in a spherical cavity

机译:球形腔中的三个硬球

获取原文
获取原文并翻译 | 示例
           

摘要

This work is devoted to furthering the understanding of few- and many-body inhomogeneous systems in the framework of the statistical mechanics of fluids. The three-body system consisting in three hard spheres (HS) confined in a spherical cavity at constant temperature is studied. Its canonical ensemble partition function and thermodynamic properties (such as the free energy, pressures, and fluid-substrate surface tension) are analytically obtained as a function of the cavity radius. This is the first time that a three-body fluid-like system is exactly solved. Symmetry relations between this system and its dual system composed of three HS surrounding a hard spherical object are analyzed. They allow to analytically obtain the canonical partition function of the dual system and its thermodynamic properties. Finally, the behavior of the many-body system of HS in contact with a hard spherical wall in the low density limit, is studied, focusing on the curvature dependence of the fluid-substrate surface tension and finding exact expressions for the Tolmans length and the second order term in curvature.
机译:这项工作致力于在流体统计力学的框架内进一步增进对多体和异体系统的理解。研究了由三个硬球(HS)组成的三体系统,该三个硬球被限制在恒定温度下的球形腔内。作为腔半径的函数,可以通过解析获得其规范的整体分配函数和热力学特性(例如自由能,压力和流体基质表面张力)。这是首次精确解决三体类流体系统。分析了该系统与其围绕硬球形物体的三个HS组成的对偶系统之间的对称关系。它们允许从分析上获得对偶系统的规范分配函数及其热力学性质。最后,研究了在低密度极限下HS与硬质球形壁接触的多体系统的行为,着重研究了流体-基体表面张力的曲率依赖性,并找到了Tolmans长度和屈服强度的精确表达式。二阶曲率项。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号