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首页> 外文期刊>The Journal of Chemical Physics >Charge regulation and ionic screening of patchy surfaces
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Charge regulation and ionic screening of patchy surfaces

机译:斑点表面的电荷调节和离子筛选

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摘要

The properties of surfaces with charge-regulated patches are studied using nonlinear Poisson-Boltzmann theory. Using a mode expansion to solve the nonlinear problem efficiently, we reveal the charging behavior of Debye-length sized patches. We find that the patches charge up to higher charge densities if their size is relatively small and if they are well separated. The numerical results are used to construct a basic analytical model which predicts the average surface charge density on surfaces with patchy chargeable groups.
机译:使用非线性Poisson-Boltzmann理论研究带电荷调节斑块的表面的特性。使用模式扩展来有效地解决非线性问题,我们揭示了德比长度大小的补丁的充电行为。我们发现,如果补丁的大小相对较小且间隔良好,则它们可以充电至更高的电荷密度。数值结果用于构建基本的分析模型,该模型可预测带有可补丁电荷基团的表面的平均表面电荷密度。

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