Exact analytical evaluation of time dependent transmission coefficient from the method of reactive flux for an inverted parabolic barrier

摘要

The paper demonstrates an elegant way of combining the normal mode analysis and the method of reactive flux to evaluate the time dependent transmission coefficient for a classical particle coupled to a set of harmonic oscillators, surmounting a one dimensional barrier. The author's analysis reproduces the results of Kohen and Tannor [J. Chem. Phys. 103, 6013 (1995)] and Bao [J. Chem. Phys. 124, 114103 (2006)]. Moreover the use of normal mode analysis has a better physical meaning. (c) 2007 American Institute of Physics.