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首页> 外文期刊>The Journal of Chemical Physics >Doorway mechanism for dissociative electron attachment to fructose
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Doorway mechanism for dissociative electron attachment to fructose

机译:解离电子附着到果糖的门机制

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摘要

Recently,the three sugars ribose,deoxyribose,and fructose have been shown to undergo dissociative electron attachment at threshold,that is,to fragment upon capture of a zero-energy electron.Here the electron acceptor properties of three fructose isomers are investigated in view of a doorway mechanism.Two key ingredients for a doorway mechanism,a weakly bound state able to support a vibrational Feshbach resonance,and a valence anion more stable than neutral fructose are characterized.Moreover,possible structures for the observed fragment anion (fructose-H2O)-are suggested.
机译:最近,已显示三种糖核糖,脱氧核糖和果糖在阈值处经历解离电子附着,即在捕获零能电子时发生断裂。在此,研究了三种果糖异构体的电子受体性能表征了门道机制的两个关键成分,即能够支持振动Feshbach共振的弱结合状态和比中性果糖更稳定的化合价阴离子。此外,观察到的碎片阴离子(果糖-H2O)的可能结构-建议。

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