Erratum:'Why hyperpolarizabilities fall short of the fundamental quantum limit'[J.Chem.Phys..121,7932 (2004)]

摘要

This errata corrects two errors that appeared in our recent paper.While these errors do not change the conclusions of the original paper,the corrections are required for our analysis to provide the correct numerical results.The conclusion of our paper was that vibronic states are not responsible for the large gap between the calculated fundamental limits and the best measured hyperpolarizabilities.Using the corrected equation under the Born-Oppenheimer approximation,we find that the vibrational contributions are even smaller than what we previously estimated,thus strengthening the conclusion.