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首页> 外文期刊>The Journal of Chemical Physics >Relativistic correction to the 1s sigma and 2p sigma electronic states of the H-2(+) molecular ion and the moleculelike states of the antiprotonic helium He+(p)over-bar
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Relativistic correction to the 1s sigma and 2p sigma electronic states of the H-2(+) molecular ion and the moleculelike states of the antiprotonic helium He+(p)over-bar

机译:对H-2(+)分子离子的1s sigma和2p sigma电子态以及反质子氦He +(p)over-bar的分子状态的相对论校正

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摘要

Effective potentials of the relativistic Breit-Pauli corrections for the 1s sigma(g) and 2p sigma(u) electron states of the H-2(+) molecular ion and the 1s sigma, 2s sigma, and 3p sigma states of the antiprotonic helium atom He+ p are calculated within the Born-Oppenheimer approximation. The variational expansion with randomly chosen exponents has been used for numerical studies. The results obtained for the Breit-Pauli effective potentials are accurate up to ten significant digits for the H-2(+) molecular ion and eight digits for the He+ p atom. (c) 2006 American Institute of Physics.
机译:H-2(+)分子离子的1s sigma(g)和2p sigma(u)电子态以及反质子氦的1s sigma,2s sigma和3p sigma态的相对论Breit-Pauli校正的有效势原子He + p在Born-Oppenheimer近似内计算。随机选择指数的变分展开已用于数值研究。 Breit-Pauli有效电势获得的结果对于H-2(+)分子离子精确到10个有效数字,对于He + p原子精确到8个数字。 (c)2006年美国物理研究所。

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