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Anisotropic lattice models of electrolytes

机译:电解质的各向异性晶格模型

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Systems of charged particles on anisotropc three-dimensional lattices are investigated theoretically using Debye-Huckel theory. It is found that the thermodynamics of these systems strongly depends on the degree of anisotropy. For weakly anisotropic simple cubic lattices, the results indicate the existence of order-disorder phase transitions and a tricritical point, while the possibility of low-density gas-liquid coexistence is suppressed. For strongly anisotropic lattices this picture changes dramatically: The low-density gas-liquid phase separation reappears and the phase diagram exhibits critical, tricritical, and triple points. For body-centered lattices, the low-density gas-liquid phase coexistence is suppressed is suppressed for all degrees of anisotropy. These results show that the effect of anisotropy in lattice models of electrolytes amounts to reduction of spatial dimensionality.
机译:使用Debye-Huckel理论从理论上研究了各向异性三维晶格上的带电粒子系统。发现这些系统的热力学强烈地取决于各向异性的程度。对于弱各向异性的简单立方晶格,结果表明存在有序-无序相变和三临界点,同时抑制了低密度气液共存的可能性。对于强各向异性的晶格,此图发生了巨大变化:低密度的气液相分离再次出现,并且相图显示出临界点,三临界点和三重点。对于以体为中心的晶格,对于所有各向异性度,都抑制了低密度气相-液相共存。这些结果表明,在电解质晶格模型中各向异性的影响等于空间维数的减小。

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