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首页> 外文期刊>The Journal of Chemical Physics >Dynamics of immersed molecules in superfluids
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Dynamics of immersed molecules in superfluids

机译:超流体中浸没分子的动力学

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摘要

The dynamics of a molecule immersed in a superfluid medium are considered. Results are derived using a classical hydrodynamic approach followed by canonical quantization. The clasical model, a rigid body immersed in incompressible fluid, permits a thorough analysis; its effective Hamilonian generalizes the usual rigid-rotor Hamiltonian. In contrast to the free rigid rotor, the immersed body is shown to have chatotic dynamics. Quantization of the classical model leads to new and experimentally verifiable features. It is shown, for instance, that chiral molecules can behave as "quantum propellers:" the rotational-translational coupling induced by the superfluid leds to a nonzero linear momentum in the ground state. The signature is a characteristic splitting of rotational absorption lines. The 1_01->1_10 line in hydrogen peroxide, for example, is predicted to split into three lines separated by as much as 0.01 cm~(-1), which is about the experimental linewidth.
机译:考虑了浸入超流体介质中的分子的动力学。使用经典的流体动力学方法,然后进行规范化量化,得出结果。经典模型是浸没在不可压缩流体中的刚体,可以进行全面分析。它的有效哈密顿量推广了通常的刚性转子哈密顿量。与自由的刚性转子相反,沉浸的物体显示为具有混沌动力学。经典模型的量化导致新的和实验可验证的功能。例如,表明手性分子可以表现为“量子推进器”:超流体引起的旋转-翻译偶联导致基态的线性动量非零。签名是旋转吸收线的特征性分离。例如,过氧化氢中的1_01-> 1_10谱线预计会分成三行,相距多达0.01 cm〜(-1),大约是实验的谱线宽度。

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