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.Energy barrier effect on transient nucleation kinetics:Nucleation flux and lag-time calculation

机译:势垒对瞬态成核动力学的影响:核通量和滞后时间计算

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摘要

Energy barrier effect on the transient nucleation kinetics is studied. For a high barrier case an advanced interpolation of the "boundary-layer"type is suggested that is valid for the entire time interval. The nucleatin kinetics for the "nucleated cluster"size n_c is described, the lag time estimate for n=n_c is given. For a low barrier case a new "similarity"solution is reported. It is shown that analytical results provide an adegquate description of the transient nucleationkinetics (in comparison with numerical solution of governing equation)for both high-barrier and low-barrier conditions.
机译:研究了能垒对瞬态成核动力学的影响。对于高障碍情况,建议使用“边界层”类型的高级插值,该插值在整个时间间隔内均有效。描述了“成核簇”大小n_c的核素动力学,给出了n = n_c的滞后时间估计。对于低屏障情况,报道了新的“相似性”解决方案。结果表明,对于高阻隔和低阻隔条件,分析结果都可以很好地描述瞬态成核动力学(与控制方程的数值解相比)。

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