Photocatalytic oxidation of primary and secondary benzylic alcohols to carbonyl compounds catalyzed by H_3PW_(12)O_(40)/SiO_2 under an O_2 atmosphere

Saeid Farhadi; Mozhgan Afshari; Mansoureh Maleki; Zaynab Babazadeh

首页> 外文期刊>Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry >Photocatalytic oxidation of primary and secondary benzylic alcohols to carbonyl compounds catalyzed by H_3PW_(12)O_(40)/SiO_2 under an O_2 atmosphere

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Photocatalytic oxidation of primary and secondary benzylic alcohols to carbonyl compounds catalyzed by H_3PW_(12)O_(40)/SiO_2 under an O_2 atmosphere

机译：H_2PW_（12）O_（40）/ SiO_2在O_2气氛下光催化氧化伯和仲苄醇为羰基化合物

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An efficient,selective and green procedure for the photocatalytic oxidation of primary and secondary benzylic alcohols to the corresponding aldehydes and ketones has been achieved using silica-encapsulated H_3PW_(12)O_(40) as a recyclable heterogeneous photocatalyst in acetonitrile under oxygen gas as the sole reoxidant of the catalyst.

机译：使用二氧化硅封装的H_3PW_（12）O_（40）作为乙腈中氧气可循环利用的非均相光催化剂，已经实现了一种高效，选择性和绿色的方法，用于将伯和仲苄醇光催化氧化为相应的醛和酮。催化剂的唯一再氧化剂。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2005年第49期|共4页
作者
Saeid Farhadi; Mozhgan Afshari; Mansoureh Maleki; Zaynab Babazadeh;
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正文语种 eng
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Benzylic alcohols; Photocatalytic; Oxidation; Polyoxometal-ates; Silica-encapsulated; H_3PW_(12)O_(40).;

机译：苯甲醇;光催化;氧化;多金属氧酸盐;二氧化硅包裹;H_3PW_（12）O_（40）。;

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1. Photocatalytic oxidation of primary and secondary benzylic alcohols to carbonyl compounds catalyzed by H_3PW_(12)O_(40)/SiO_2 under an O_2 atmosphere [J] . Saeid Farhadi, Mozhgan Afshari, Mansoureh Maleki, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2005,第49期

机译：H_2PW_（12）O_（40）/ SiO_2在O_2气氛下光催化氧化伯和仲苄醇为羰基化合物
2. Photocatalytic oxidation of primary and secondary benzylic alcohols to carbonyl compounds catalyzed by H_3PW_(12)O_(40)/SiO_2 under an O_2 atmosphere [J] . Saeid Farhadi, Mozhgan Afshari, Mansoureh Maleki, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2005,第49期

机译：H_2PW_（12）O_（40）/ SiO_2在O_2气氛下光催化氧化伯和仲苄醇为羰基化合物
3. Sol-Gel Silica-Supported 12-Tungstosilicic Acid (H_4SiW_(12)O_(40)/SiO_2) as a Heterogeneous Photocatalyst for Efficient and Selective Oxidation of Benzylic Alcohols with O_2 under Photoirradiation [J] . Saeid Farhadi, Mansoureh Maleki, Zaynab Babazadeh Acta Chimica Slovenica . 2006,第1期

机译：Sol-Gel二氧化硅负载的12-钨硅酸（H_4SiW_（12）O_（40）/ SiO_2）作为多相光催化剂，用于在光辐照下用O_2有效和选择性地氧化苯甲醇。
4. Direct synthesis of dimethyl carbonate form methanol and carbon dioxide using H_3PW_(12)O_(40)/Ce_(0.1)Ti_(0.9)O_2 with ionic liquid catalysts [C] . Ru Chun Wu, Tiao Xie, Mei Li International Conference on Advances in Materials and Manufacturing Processes . 2012

机译：使用离子液体催化剂直接合成碳酸二甲酯和二氧化碳的二甲基二氧化碳和二氧化碳，用离子液体催化剂（0.1）o_2
5. Palladium-catalyzed isomerization of epoxides to carbonyl compounds: Scope and mechanism. [D] . Kulasegaram, Sanjitha. 1997

机译：钯催化环氧化物异构化为羰基化合物：范围和机理。
6. Cu-catalyzed enantioselective synthesis of tertiary benzylic copper complexes and their in situ addition to carbonyl compounds [O] . Fengchang Cheng, Wenxin Lu, Wei Huang, 2018

机译：铜催化的对叔苄基铜配合物的对映选择性合成及其在羰基化合物中的原位加成
7. Synthesis of Adipic Acid Catalyzed by H_3PW_(12)O_(40) [O] . 李华明(海南师范学院化学系), 纪明慧(海南师范学院化学系), 林海强, 2003

机译：H_3PW_（12）O_（40）催化合成己二酸
8. Photocatalytic Oxidation of Multifunctional Organic Molecules. The Effect of anIntramolecular Aryl Thioether Group on the Semiconductor-Mediated Oxidation/Dehydrogenation of a Primary Aliphatic Alcohol [R] . Fox, M. A., Abdel-Wahab, A. A. 1990

机译：多功能有机分子的光催化氧化。非分子芳基硫醚基团对半导体介导的伯脂肪醇氧化/脱氢的影响

Photocatalytic oxidation of primary and secondary benzylic alcohols to carbonyl compounds catalyzed by H_3PW_(12)O_(40)/SiO_2 under an O_2 atmosphere

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