(PCy3)(2)Cl2Ru=CHPh Catalyzed Kharasch additions. Application in a formal olefin carbonylation

Lee BT; Schrader TO; Martin-Matute B; Kauffman CR; Zhang P; Snapper ML

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(PCy3)(2)Cl2Ru=CHPh Catalyzed Kharasch additions. Application in a formal olefin carbonylation

机译：（PCy3）（2）Cl2Ru = CHPh催化的Kharasch加成物。在正式的烯烃羰基化中的应用

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(PCy3)(2)Cl2Ru=CHPh-catalyzed Kharasch additions of trihaloalkanes across olefins provide polyhalogenated adducts, which upon hydrolysis furnish alpha,beta-unsaturated ketones, aldehydes, or gamma-hydroxybutenolides. This two-step process represents an overall acylation or carbonylation of an olefin. (C) 2004 Elsevier Ltd. All rights reserved.

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《Tetrahedron》 |2004年第34期|共6页
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Lee BT; Schrader TO; Martin-Matute B; Kauffman CR; Zhang P; Snapper ML;
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正文语种 eng
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Kharasch; metathesis; radical; carbonylation; TRANSFER RADICAL POLYMERIZATION; BETA-ACETYLACRYLIC ACID; ORGANIC-SYNTHESIS; CHAIN REACTIONS; COMPLEXES; HYDROFORMYLATION; CYCLIZATIONS; ACTIVATION; CARBENE; DESIGN;

机译：Kharasch;复分解;自由基;羰基化;转移自由基聚合;BET-乙酰丙烯酸;有机合成;链反应;络合物;加氢甲酰化;环化;活化作用;碳;设计;

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1. (PCy3)(2)Cl2Ru=CHPh Catalyzed Kharasch additions. Application in a formal olefin carbonylation [J] . Lee BT, Schrader TO, Martin-Matute B, Tetrahedron . 2004,第34期

机译：（PCy3）（2）Cl2Ru = CHPh催化的Kharasch加成物。在正式的烯烃羰基化中的应用
2. Hydrogenation of styrene-butadiene rubber catalyzed by Ru(CH=CHPh)Cl(CO)(PCy3)(2) [J] . Pan QM, Rempel GL Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation . 2004,第8期

机译：Ru（CH = CHPh）Cl（CO）（PCy3）（2）催化的丁苯橡胶加氢
3. Cross-coupling of vinyldisilacyclobutane with olefins catalyzed by [RuH(Cl)(CO)(PCy3)(2)] [J] . Jankowska M, Shuvalova O, Bespalova N, Journal of Organometallic Chemistry . 2005,第20期

机译：[RuH（Cl）（CO）（PCy3）（2）]催化乙烯基二硅环丁烷与烯烃的交叉偶联
4. BINARY BLENDS OF EVA AND METALLOCENE-CATALYZED ETHYLENE-α-OLEFIN COPOLYMERS FOR FILM APPLICATIONS [C] . M. Kontopoulou, J.A. Lee, L C. Huang, 59th Society of Plastics Engineers Annual Conference . 2001

机译：EVA和金属茂催化的乙烯-α-烯烃共聚物的二元共混物
5. 1. Axially-chiral 7-membered N-heterocyclic carbenes: Synthesis and application to palladium-catalyzed intramolecular aerobic oxidation of olefins 2. Development of palladium-catalyzed aerobic oxidative olefin amination reactions [D] . Scarborough, Christopher C. 2008

机译：1.轴向手性7元N-杂环卡宾：烯烃的钯催化分子内需氧氧化的合成及应用2.钯催化需氧氧化烯烃胺化反应的发展
6. Ruthenium-catalyzed formal sp3 C–H activation of allylsilanes/esters with olefins: efficient access to functionalized 13-dienes [O] . Dattatraya H. Dethe, Nagabhushana C. Beeralingappa, Saikat Das, 2021

机译：钌催化的正式Sp3 C-H与烯烃的烯丙基/酯的活化：有效进入官能化13-二烯
7. Toward Green Acylation of (Hetero)arenes: Palladium-Catalyzed Carbonylation of Olefins to Ketones [O] . Jie Liu, Zhihong Wei, Haijun Jiao, 2017

机译：朝向（异质）的绿色酰化：钯催化烯烃羰基化至酮

(PCy3)(2)Cl2Ru=CHPh Catalyzed Kharasch additions. Application in a formal olefin carbonylation

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