Decorated MCM-41/polyethylene hybrids: Crystalline details and viscoelastic behavior

摘要

Polyethylene-based nanocomposites have been prepared by in-situ polymerization of ethylene with mesostructured MCM-41. Different approaches are used to improve interfacial adhesion between components, high density polyethylene (HDPE) matrix and MCM-41. These consist either of the incorporation of UA in the polymer chains by copolymerization in a very small content or of the modification of MCM-41 surface with the system based on undecenoic acid, UA/triisobutylaluminum, TIBA, before polymerization. The materials attained exhibit minimal changes in the crystallinity resulting from first melting process although a slight increase of long spacing at room temperature is seen as MCM-41 is incorporated in the hybrids. Moreover, a confinement effect is noticed and, thus, a delay in the crystallization process of the macrochains within pores and channels is detected. These novel self-reinforced nanocomposites show higher stiffness than other similar hybrids with poorer interfacial adhesion. Accordingly, they exhibit an enhancement in their mechanical performance without changing the final processing temperature since T_m is the same for all of the specimens.