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首页> 外文期刊>Colloid journal >Adsorption and photocatalytic oxidation of acetone and diethyl sulfide on FeOOH aerosol
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Adsorption and photocatalytic oxidation of acetone and diethyl sulfide on FeOOH aerosol

机译:FeOOH气溶胶对丙酮和二乙基硫的吸附和光催化氧化

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Superfine FeOOH powder in an aerosol state with a particle size of about 3 nm has been studied in the processes of reactive adsorption and photocatalytic oxidation of acetone and diethyl sulfide vapors in air. The aerosol (5 g) is sprayed with a Helmholtz resonator placed into the center of a 100-L plastic chamber. Spraying is completed in 2 min, and the aerosol settles down within a time of less than 5 min. Rapid partial adsorption of acetone and diethyl sulfide on aerosol nanoparticles with characteristic times of 1 and 1.3 min, respectively, has been observed. FeOOH exhibits no photocatalytic activity with respect to acetone oxidation. Diethyl sulfide is oxidized with the formation of acetaldehyde as an intermediate product and CO and CO2 as the final products.
机译:在空气中丙酮和二乙基硫醚蒸气的反应吸附和光催化氧化过程中,已经研究了气溶胶状态的超细FeOOH粉末,其粒径约为3 nm。将5 g的气雾剂喷入置于100 L塑料腔室中央的亥姆霍兹共振器。喷涂在2分钟内完成,气溶胶在不到5分钟的时间内沉淀下来。观察到丙酮和二乙基硫醚在特征时间分别为1和1.3分钟的气溶胶纳米颗粒上的快速部分吸附。 FeOOH对丙酮氧化没有光催化活性。乙二硫醚被氧化,形成乙醛作为中间产物,而生成CO和CO2作为最终产物。

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