A New Two-Dimensional Silver Coordination Polymer Constructed by 1,3-Bis(4-pyridyl)propane and 2,6-Dichlorophenylacetic Acid: Synthesis, Structure, Luminescence and Thermal Stable Properties

摘要

A novel complex 1 of {[Ag(bpp)(dcpa)] H2O}_n [Hdcpa: 2,6-dichlorophenylacetic acid; bpp: 1,3-bis(4-pyridyl)propane] was synthesized and characterized by elemental analysis, IR. TGA. X-ray single crystal diffraction. The carboxylate oxygens of the Hdcpa ligands connect one Ag(I) ion in bidentate chelating mode to form mononuclear silver building blocks, which are into a ID infinite chain through trans+bpp ligands. A two-dimensional network consist of adjacent Ag-bpp chain through Ag-Ag interaction. Furthermore, the luminescent property of complex 1 was investigated at room temperature. CCDC: 996495.