Reaction Mechanism for Selective Oxidation of Anethole to Anisaldehyde by Hydrogen Peroxide in Presence of Ferric Vanadate

Xingdong Yao; Caihua Peng; Zhanwang Shi

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Reaction Mechanism for Selective Oxidation of Anethole to Anisaldehyde by Hydrogen Peroxide in Presence of Ferric Vanadate

机译：钒酸铁存在下过氧化氢对茴香脑选择性氧化为茴香醛的反应机理

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The reaction mechanism and kinetics for the oxidation of anethole to anisaldehyde by H2O2 in the presence of ferric vanadate have been investigated. The results show it is a homogeneous system with vanadium oxodiperoxo ton as the actual oxidant. The reaction follows the pseudo-first order rate equation. Free radical reaction mechanism has been verified by DPPH. A plausible reaction mechanism has been proposed based on the experimental results.

机译：研究了钒铁酸存在下H2O2将茴香脑氧化为茴香醛的反应机理和动力学。结果表明，该体系是均一的体系，其中氧代二过氧钒为实际氧化剂。该反应遵循伪一级速率方程。 DPPH已验证了自由基的反应机理。根据实验结果，提出了合理的反应机理。

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《Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry》 |2014年第17期|共4页
作者
Xingdong Yao; Caihua Peng; Zhanwang Shi;
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正文语种 eng
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关键词
Anethole; Anisaldehyde; Ferric vanadate; Hydrogen peroxide; Reaction mechanism.;

机译：茴香脑;茴香醛;钒酸铁;过氧化氢;反应机理;

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1. Reaction Mechanism for Selective Oxidation of Anethole to Anisaldehyde by Hydrogen Peroxide in Presence of Ferric Vanadate [J] . Xingdong Yao, Caihua Peng, Zhanwang Shi Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry . 2014,第17期

机译：钒酸铁存在下过氧化氢对茴香脑选择性氧化为茴香醛的反应机理
2. Superoxide dismutase and Fenton chemistry. Reaction of ferric-EDTA complex and ferric-bipyridyl complex with hydrogen peroxide without the apparent formation of iron(II) [J] . J M C Gutteridge, L Maidt, L Poyer The biochemical journal . 1990,第1期

机译：超氧化物歧化酶和芬顿化学。铁-EDTA络合物和铁-联吡啶络合物与过氧化氢的反应而没有明显形成铁（II）
3. Kinetics and Mechanisms of Decomposition Reaction of Hydrogen Peroxide in Presence of Metal Complexes [J] . IBRAHIM A.SALEM, MOHAMED EL-MAAZAWI, AMED B.ZAKI International Journal of Chemical Kinetics . 2000,第11期

机译：金属络合物存在下过氧化氢分解反应的动力学及机理
4. Photochemical Degradation of Azo Dyes in the Presence of Hydrogen Peroxide and Hematite under Visible Light Irradiation: Surface Complex Forming and Reaction Mechanism [C] . Yu-Chao Tang, Xian-Huai Huang, Han-Qing Yu International Conference on Advanced Engineering Materials and Technology . 2011

机译：可见光照射下亚氧化氢和赤铁矿存在下偶氮染料的光化学劣化：表面复合成形和反应机理
5. MECHANISMS AND KINETICS OF OZONE AND HYDROXYL RADICAL REACTIONS WITH MODEL ALIPHATIC AND OLEFINIC COMPOUNDS (WATER, AQUEOUS PHASE, HYDROGEN PEROXIDE, ULTRAVIOLET RADIATION). [D] . MASTEN, SUSAN JANE. 1986

机译：与模型脂族和烯烃化合物（水，水相，过氧化氢，紫外线辐射）的臭氧和羟基自由基反应的机理和动力学。
6. Superoxide dismutase and Fenton chemistry. Reaction of ferric-EDTA complex and ferric-bipyridyl complex with hydrogen peroxide without the apparent formation of iron(II). [O] . J M Gutteridge, L Maidt, L Poyer 1990

机译：超氧化物歧化酶和芬顿化学。铁-EDTA络合物和铁-联吡啶基络合物与过氧化氢的反应而没有明显的铁（II）形成。
7. Superoxide dismutase and Fenton chemistry. Reaction of ferric-EDTA complex and ferric-bipyridyl complex with hydrogen peroxide without the apparent formation of iron(II). [O] . Gutteridge, J M, Maidt, L, Poyer, L 1990

机译：超氧化物歧化酶和芬顿化学。铁-EDTA络合物和铁-联吡啶基络合物与过氧化氢的反应而没有明显的铁（II）形成。
8. Reactions Involving Hydrogen Peroxide, Iodine, and Iodate Ion. 6. Oxidation of Iodine by Hydrogen Peroxide at 50 deg C. [R] . Liebhafsky, H. A., McGavock, W. C., Reyes, R. J., 1977

机译：涉及过氧化氢，碘和碘酸根离子的反应。 6.过氧化氢在50℃下氧化碘

Reaction Mechanism for Selective Oxidation of Anethole to Anisaldehyde by Hydrogen Peroxide in Presence of Ferric Vanadate

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