Large-Scale, Highly Efficient, and Green Liquid-Exfoliation of Black Phosphorus in Ionic Liquids

摘要

We developed a facile, large-sole, and environmentally friendly liquid-exfoliation method to produce stable and high-concentration dispersions of mono- to few-layer black phosphorus (BP) nanosheets from bulk BP using nine ionic liquids. The prepared suspensions can stabilize without any obvious sedimentation and aggregation in ambient air for one month. In particular, the concentration (up to 0.95 mg mL(-1)) of BP nanoflakes obtained in 1-hydroxyethyl-3-methylimidazolium trifluoromethansulfonate ([HOEMIM]-[TfO]) is the highest reported for BP nanosheets dispersions. This work provides new opportunities for preparing atomically thin BP nanosheets in green; large-scale, and highly concentrated processes and achieving its in situ application.