Effect of internal pressure and gas/liquid interface area on the CO mass transfer coefficient using hollow fibre membranes as a high mass transfer gas diffusing system for microbial syngas fermentation

摘要

This study proposed a submerged hollow fibre membrane bioreactor (HFMBR) system capable of achieving high carbon monoxide (CO) mass transfer for applications in microbial synthesis gas conversion systems. Hydrophobic polyvinylidene fluoride (PVDF) membrane fibres were used to fabricate a membrane module, which was used for pressurising CO in water phase. Pressure through the hollow fibre lumen (P) and membrane surface area per unit working volume of the liquid (A_S/V_L) were used as controllable parameters to determine gas-liquid volumetric mass transfer coefficient (k_La) values. We found a k_La of 135.72 h~(-1) when P was 93.76 kPa and A_S/V_L was fixed at 27.5 m~(-1). A higher k_La of 155.16 h~(-1) was achieved by increasing A_S/V_L to 62.5 m~(-1) at a lower P of 37.23 kPa. Practicality of HFMBR to support microbial growth and organic product formation was assessed by CO/CO_2 fermentation using Eubacterium limosum KIST612.