Thermal degradation behavior and kinetic analysis of ultra high molecular weight polyethylene based multi-walled carbon nanotube nanocomposites prepared via in-situ polymerization

摘要

Thermal degradation behavior of multi-wall carbon nanotubes (MWCNTs)/ultra high molecular weight polyethylene (UHMWPE) nanocomposites, with different nanotubes contents (0.5, 1.5 and 3.5 wt%) prepared via in-situ polymerization technique have been investigated using thermal gravimetric analysis (TGA). TGA spectra revealed that these nanocomposites had enhanced thermal stability and no significant mass loss (<0.4 wt%) occurred up to 350°C. Thermal degradation of these UHMWPE/MWCNT nanocomposites was investigated in terms of parameters such as the onset temperature of degradation (T _(10)), the decomposition temperature at 50% wt loss (T _(50)), the degradation temperature of maximum rate of the weight loss (T _m), and the residual yields (W _R) from TGA. The degradation activation energies (E) of virgin UHMWPE and its nanocomposites were estimated using the Friedman, the Ozawa, Flynn, and Wall (OFW), and the Kissinger's methods. Results indicated that the degradation activation energy for the virgin UHMWPE was 281.3 kJ/mol. The activation energy increased with increasing nanotube loading up to 1.5 wt% indicating that MWCNTs had a stabilizing effect on the degradation of the matrix. However, loadings of 3.5 wt% of nanotube or more could slightly decrease the activation energy. The decrease in the activation energy for degradation of nanocomposites with higher MWCNT concentrations might be attributed to the catalytic effects of nanotubes and polymerization catalyst residues. The model fitting method indicated a mechanism of n ~(th)-order auto-catalysis from the form of the conversion curves for UHMWPE/MWCNTs nanocomposites prepared via in-situ polymerization.