首页> 外文期刊>Journal of Heterocyclic Chemistry: The International Journal of Heterocyclic Chemistry >A novel, facile, simple and convenient oxidative aromatization of Hantzsch 1,4-dihydropyridines to pyridines using polymeric iodosobenzene with KBr
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A novel, facile, simple and convenient oxidative aromatization of Hantzsch 1,4-dihydropyridines to pyridines using polymeric iodosobenzene with KBr

机译:聚合的碘代苯与KBr将Hantzsch 1,4-二氢吡啶氧化为吡啶的新颖,简便,简便的氧化芳构化反应

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摘要

An easy, safe, effective and handy method for oxidative aromatization of Hantzsch 1,4-dihydropyridines catalyzed by hypervalent iodine (iodosobenzene) and potassium bromide to corresponding pyridine derivatives in high-yields and within short span of time was described. Dealkylation in case of 4-n-alkyl substituted 1,4-dihydropyridines was not obtained.
机译:描述了一种简便,安全,有效且方便的方法,该方法可在高收率下且短时间内将高价碘(碘代苯)和溴化钾催化氧化汉茨1,4-二氢吡啶氧化为相应的吡啶衍生物。在4-正烷基取代的1,4-二氢吡啶的情况下未获得脱烷基化。

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