Syntheses and crystal structures of two Zn(II) complexes, [Zn(Fura)_2(2,2-bipy)(H2O)] and [Zn(mu-dnbc)_2] (Fura = Furoic acid, 2,2'-bpy = 2,2/-bipyridine, dnba = 3,5-dinitrobenzoic acid)

XIAN-FU ZHENG; XIAO-QING SHENJ; XIN-SHENG WAN

首页> 外文期刊>Journal of Coordination Chemistry >Syntheses and crystal structures of two Zn(II) complexes, [Zn(Fura)_2(2,2-bipy)(H2O)] and [Zn(mu-dnbc)_2] (Fura = Furoic acid, 2,2'-bpy = 2,2/-bipyridine, dnba = 3,5-dinitrobenzoic acid)

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Syntheses and crystal structures of two Zn(II) complexes, [Zn(Fura)_2(2,2-bipy)(H2O)] and [Zn(mu-dnbc)_2] (Fura = Furoic acid, 2,2'-bpy = 2,2/-bipyridine, dnba = 3,5-dinitrobenzoic acid)

机译：两种Zn（II）配合物[Zn（Fura）_2（2,2-bipy）（H2O）]和[Zn（mu-dnbc）_2]的合成和晶体结构（Fura =呋喃甲酸，2,2'- bpy = 2,2 /-联吡啶，dnba = 3,5-二硝基苯甲酸）

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Two Zn(II) complexes, [Zn(Fura)_2(2,2'-bpy)(H_2O)] (1) and [Zn(mu-dnbc)_2] (2), have been synthesized and characterized by X-ray diffraction and IR spectra. 1 is a quaternary Zn(II) complex with ZnN_2O_3 configuration distorted square pyramid geometry; 2 is a Zn(II) coordination polymer with ID double-helical chains bridged by 3,5-dinitrobenzoic acid.

机译：合成了两种Zn（II）配合物[Zn（Fura）_2（2,2'-bpy）（H_2O）]（1）和[Zn（mu-dnbc）_2]（2），并通过X-射线衍射和红外光谱。图1是具有ZnN_2O_3构型的扭曲的四棱锥几何形状的季Zn（II）配合物; 2是具有被3，5-二硝基苯甲酸桥连的ID双螺旋链的Zn（II）配位聚合物。

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来源
《Journal of Coordination Chemistry》 |2007年第14期|共9页
作者
XIAN-FU ZHENG; XIAO-QING SHENJ; XIN-SHENG WAN;
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正文语种 eng
中图分类无机化学;
关键词
Zn(II) complex; Furoic acid; Coordination polymer; 3; 5-dinitrobenzoic acid;

机译：Zn（II）配合物;糠酸;配位聚合物;3;5-二硝基苯甲酸;

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1. Syntheses and crystal structures of two Zn(II) complexes, [Zn(Fura)_2(2,2-bipy)(H2O)] and [Zn(mu-dnbc)_2] (Fura = Furoic acid, 2,2'-bpy = 2,2/-bipyridine, dnba = 3,5-dinitrobenzoic acid) [J] . XIAN-FU ZHENG, XIAO-QING SHENJ, XIN-SHENG WAN Journal of Coordination Chemistry . 2007,第12a14期

机译：两种Zn（II）配合物[Zn（Fura）_2（2,2-bipy）（H2O）]和[Zn（mu-dnbc）_2]的合成和晶体结构（Fura =呋喃甲酸，2,2'- bpy = 2,2 /-联吡啶，dnba = 3,5-二硝基苯甲酸）
2. Syntheses, crystal structures and properties of Zn(II) and Cd(II) complexes derived from N-(o-nitrophenyl)-N '-(methoxycarbonyl)thiourea(H(2)omt) and 2,2 '-bipyridine(bpy) or o-phenanthroline(phen) [J] . Shen X., Kang BS., Liu Y., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第23a24期

机译：N-（邻硝基苯基）-N'-（甲氧基羰基）硫脲（H（2）omt）和2,2'-联吡啶（bpy）衍生的Zn（II）和Cd（II）配合物的合成，晶体结构和性质）或邻菲咯啉（phen）
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4. Synthesis, Structures and Properties of Two New Three-dimensional Ce(III) Coordination Polymers with 2,2'-bipyridine-4,4'-dicarboxylic Acid [C] . Ruiping Zheng, Huiyuan Chen, Junjie He, International Conference on Advanced Engineering Materials and Technology . 2013

机译：用2,2'-硼烷-4,4'-二羧酸的两种新三维Ce（III）配位聚合物的合成，结构和性质
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机译：I.水溶液中汞电极上一氧化二氮和亚硝酸的电化学二。铁（III）和铁（II）的2,2'-联吡啶络合物的电化学和水解动力学；多种铁络合物的电化学动力学参数。三，铀（IV）-水溶液（氧化氘）中铀（IV）-乙撑双氨基乙酸复合物的质子核磁共振研究
6. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of Mn(ph)(Phen)2(H2O)· 4H2O Mn(Phen)2(H2O)22(Isoph)2(Phen)· 12H2O and {Mn(Isoph)(bipy)4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 110-Phenanthroline; bipy = 22-Bipyridine) [O] . Michael Devereux, Malachy McCann, Vanessa Leon, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：Mn（ph）（Phen）2（H2O）·4H2OMn（Phen）2（H2O）2 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{Mn（Isoph）（bipy） 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 110-邻菲咯啉; bipy = 22 -联吡啶）
7. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of [Mn(ph)(Phen)2(H2O)]· 4H2O, [Mn(Phen)2(H2O)2]2(Isoph)2(Phen)· 12H2O and {[Mn(Isoph)(bipy)]4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 1,10-Phenanthroline; bipy = 2,2-Bipyridine) [O] . Devereux, Michael, McCann, Malachy, Leon, Vanessa, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：[Mn（ph）（Phen）2（H2O）]·4H2O，[Mn（Phen）2（H2O）2] 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{[Mn（Isoph）（bipy）] 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 1,10-邻菲咯啉; bipy = 2,2 -联吡啶）
8. Excited-State Acid-Base Reactions of Dicyanobis(2,2'-bipyridine)ruthenium(II) and Dicyanobis(1,10-phenanthroline)ruthenium(II) [R] . Peterson, S. H., Demas, J. N. 1978

机译：双氰基（2,2'-联吡啶）钌（II）和二氰基双（1,10-菲咯啉）钌（II）的激发态酸碱反应

Syntheses and crystal structures of two Zn(II) complexes, [Zn(Fura)_2(2,2-bipy)(H2O)] and [Zn(mu-dnbc)_2] (Fura = Furoic acid, 2,2'-bpy = 2,2/-bipyridine, dnba = 3,5-dinitrobenzoic acid)

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