A novel synthesis of unsymmetrical selenides via the cleavage of Se-Se bond by Sm/cat.CoCl2 system

Chen RN; Su WK; Zhong WH

首页> 外文期刊>Journal of Chemical Research. Synopses >A novel synthesis of unsymmetrical selenides via the cleavage of Se-Se bond by Sm/cat.CoCl2 system

【24h】

A novel synthesis of unsymmetrical selenides via the cleavage of Se-Se bond by Sm/cat.CoCl2 system

机译：通过Sm / cat.CoCl2系统裂解Se-Se键的新方法合成不对称硒化物

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Promoted by Sm/cat. CoCl2 system, the Se-Se bond of diaryldiselenides was easily cleaved to form a "living" intermediate, which reacted readily with alkyl halides to afford unsymmetrical alkylarylselenides in good yields under mild and neutral reaction conditions.

机译：由Sm / cat推广。在CoCl2系统中，二芳基二硒化物的Se-Se键易于断裂形成“活性”中间体，该中间体易于与烷基卤化物反应，在温和和中性的反应条件下以良好的收率得到不对称的烷基芳基硒化物。

著录项

来源
《Journal of Chemical Research. Synopses》 |2005年第10期|共2页
作者
Chen RN; Su WK; Zhong WH;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Sm/CoCl2 system; Se-Se bond cleavage; diaryldiselenides; unsymmetrical alkylarylselenides; ORGANIC-SYNTHESIS; REAGENTS; ACIDS;

机译：Sm / CoCl2体系;Se-Se键断裂;二芳基二硒化物;不对称烷基芳基硒化物;有机合成;试剂;酸;

相似文献

外文文献
中文文献
专利

1. A novel synthesis of unsymmetrical selenides via the cleavage of Se-Se bond by Sm/cat.CoCl2 system [J] . Chen RN, Su WK, Zhong WH Journal of Chemical Research. Synopses . 2005,第10期

机译：通过Sm / cat.CoCl2系统裂解Se-Se键的新方法合成不对称硒化物
2. Reductive cleavage of Se-Se bond by Sm/NiCl_2 or Sm/NiCl_2.6H_2O system :A novel preparation of unsymmetrical aryl selenides [J] . R.E.Chen, W.K.Su Journal of the Indian Chemical Society . 2005,第11期

机译：Sm / NiCl_2或Sm / NiCl_2.6H_2O系统对Se-Se键的还原性裂解：一种不对称芳基硒化物的新制备方法
3. Reductive cleavage of the Se-Se bond by the Sm-Me3SiCl-H2O system: Preparation of unsymmetrical phenyl selenides [J] . Wang L., Zhang YM. Journal of Chemical Research. Synopses . 1998,第9期

机译：Sm-Me3SiCl-H2O系统对Se-Se键的还原裂解：不对称苯基硒化物的制备
4. Magnesium-Induced Copper-Catalyzed Preparation of Unsymmetrical Diaryl Sulfides from Aryl Iodides and Bisulfide Compounds via Cleavage of S-S Bond [C] . Nobukazu Taniguchi, Tetsuo Onami Symposium on Organometallic Chemistry . 2004

机译：镁催化铜催化的非对称二芳基硫化物制备来自芳基碘和双硫化物化合物的S-S键
5. Part I. Palladium-catalyzed alkenylation and alkynylation of nucleosides in aqueous media. Part II. Palladium-catalyzed carbon-selenium bond formation for unsymmetrical diaryl selenides. [D] . Cho, Joon Hyung. 2007

机译：第一部分：水介质中钯催化的核苷的烯基化和炔基化。第二部分非对称二芳基硒化物的钯催化碳-硒键形成。
6. Photoinduced synthesis of unsymmetrical diaryl selenides from triarylbismuthines and diaryl diselenides [O] . Yohsuke Kobiki, Shin-ichi Kawaguchi, Takashi Ohe, 2013

机译：由三芳基双变异蛋白和二芳基二硒化物光诱导合成不对称的二芳基硒化物
7. Ruthenium(III) chloride catalyzed efficient synthesis of unsymmetrical diorganyl selenides via cleavage of dibenzyl and diphenyl diselenides in the presence of zinc [O] . Zhao XD, Yu ZK, Yan SG, 2005

机译：Ruthenium(III) chloride catalyzed efficient synthesis of unsymmetrical diorganyl selenides via cleavage of dibenzyl and diphenyl diselenides in the presence of zinc
8. Tetrakis(methylaminobis(Difluorophosphine))Carbonyldiiron: Unsymmetrical Bonding of Methylaminobis(Difluorophosphine) to a Pair of Transition Metals Involving Phosphorus-Nitrogen Bond Cleavage. [R] . Newton, M. G., King, R. B., Chang, M., 1977

机译：四（甲基氨基双（二氟膦））羰基二铁：甲基氨基双（二氟膦）与一对涉及磷 - 氮键断裂的过渡金属的不对称键合。

A novel synthesis of unsymmetrical selenides via the cleavage of Se-Se bond by Sm/cat.CoCl2 system

摘要

著录项

相似文献

相关主题

期刊订阅