Kinetics and mechanism of the oxidation of glyoxylic acid by peroxodisulfate induced by irradiation with visible light of aqueous solutions containing tris (2,2'-bypyridine)ruthenium(II) ion

Vijai N; Suniti; Khandelwal CL; Sharma PD

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Kinetics and mechanism of the oxidation of glyoxylic acid by peroxodisulfate induced by irradiation with visible light of aqueous solutions containing tris (2,2'-bypyridine)ruthenium(II) ion

机译：含三（2,2'-吡啶）钌（II）离子水溶液的可见光照射引起的过二硫酸盐氧化乙醛酸的动力学和机理

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The kinetics of light-induced oxidation of glyoxylic acid in the presence of [Ru(bipy)(3)(2+)] as photo-catalyst have been studied. The observed kinetic rate law is given by -d[S2O82-]/dt = k(q)I(a)phi[S2O82-]/k(0)+k(q)[S2O82-] The reaction events are governed by the following scheme.

机译：研究了在[Ru（bipy）（3）（2+）]作为光催化剂存在下光诱导的乙醛酸氧化的动力学。观察到的动力学速率定律由下式给出：-d [S2O82-] / dt = k（q）I（a）phi [S2O82-] / k（0）+ k（q）[S2O82-]以下方案。

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《Journal of Chemical Research. Synopses》 |2005年第12期|共4页
作者
Vijai N; Suniti; Khandelwal CL; Sharma PD;
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正文语种 eng
中图分类化学;
关键词
kinetics; mechanism; light; photocatalyst sensitised; ELECTRON-TRANSFER; COMPLEXES; PEROXYDISULFATE; PHOTOCHEMISTRY; PEROXODIPHOSPHATE; TRIS(BIPYRIDYL)RUTHENIUM(II); PEROXOMONOSULFATE; POLYMERIZATION; RUTHENIUM(II); PHOTOPHYSICS;

机译：动力学;机理;光;光敏化的光触媒;电子转移;络合物;过氧二硫酸盐;光化学;过氧磷酸盐;三（联吡啶）钌（II）;过氧单硫酸盐;聚合;钌（II）;

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1. Kinetics and mechanism of the oxidation of glyoxylic acid by peroxodisulfate induced by irradiation with visible light of aqueous solutions containing tris (2,2'-bypyridine)ruthenium(II) ion [J] . Vijai N, Suniti, Khandelwal CL, Journal of Chemical Research. Synopses . 2005,第12期

机译：含三（2,2'-吡啶）钌（II）离子水溶液的可见光照射引起的过二硫酸盐氧化乙醛酸的动力学和机理
2. Light induced electron transfer reactions:kinetics and mechanism of oxidation of hexacyanoferrate(II) by peroxodisulphate induced by irradiation of visible light in presence of tris(2,2'-bipyridine)ruthenium(II) ion photocatalyst in aqueous solutions [J] . Savita Bansal, Seema Sharma, C.L.Khandelwal, Journal of the Indian Chemical Society . 2004,第12期

机译：光诱导的电子转移反应：在水溶液中三（2,2'-联吡啶）钌（II）离子光催化剂存在下，可见光辐射引起的过二硫酸盐过氧二硫酸盐氧化六氰铁酸酯（II）的动力学和机理
3. KINETICS AND MECHANISM OF ELECTRON TRANSFER REACTIONS:OXIDATION OF HYPOPHOSPHORUS ACID BY PEROXODISULPHATE INDUCED BY IRRADIATION WITH VISIBLE LIGHT IN AN AQUEOUS SOLUTION CONTAINING tris(2,2-BIPYRIDINE)RUTHENIUM(II)ION [J] . S.BANSAL, N.K.SOM, C.L.KHANDELWAL Oxidation Communications . 2007,第4期

机译：电子传递反应的动力学和机理：可见光在含三（2,2-双联吡啶）钌（II）离子的水溶液中过氧化二氧过硫酸盐氧化过磷酸
4. KINETICS AND MECHANISM OF RUTHENIUM(III) AND OSMIUM(VIII) CATALYZED OXIDATION OF DOPAMINE WITH BROMAMINE-B IN ACID AND ALKALINE MEDIA [C] . Puttaswamy, Nirmala Vaz 3rd International Symposium on Reaction Kinetics and the Development and Operation of Catalytic Processes, Apr 22-25, 2001, Oostende, Belgium . 2001

机译：酸性和碱性介质中溴（R）和溴（B）催化多巴胺（R）和III（O）和OS（VIII）催化的动力学和机理
5. I. THE ELECTROCHEMISTRY OF NITRIC OXIDE AND A NITROUS ACID AT A MERCURY ELECTRODE IN AQUEOUS SOLUTIONS. II. ELECTROCHEMISTRY AND HYDROLYSIS KINETICS OF THE 2,2'-BIPYRIDINE COMPLEXES OF IRON(III) AND IRON(II); ELECTROCHEMICAL KINETIC PARAMETERS FOR SEVERAL IRON COMPLEXES. III. PROTON NUCLEAR MAGNETIC RESONANCE STUDIES OF URANIUM(IV)-ETHYLENE DIAMINETETRAACETIC ACID COMPLEXES IN AQUEOUS (DEUTERIUM-OXIDE) SOLUTIONS. [D] . EHMAN, DEWAYNE LEE. 1969

机译：I.水溶液中汞电极上一氧化二氮和亚硝酸的电化学二。铁（III）和铁（II）的2,2'-联吡啶络合物的电化学和水解动力学；多种铁络合物的电化学动力学参数。三，铀（IV）-水溶液（氧化氘）中铀（IV）-乙撑双氨基乙酸复合物的质子核磁共振研究
6. Kinetics and Mechanisms of the Chromium(III) Reactions with 24- and 25-Dihydroxybenzoic Acids in Weak Acidic Aqueous Solutions [O] . Kimon Zavitsanos, Athinoula L. Petrou 2010

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7. Light-induced Electron-transfer Reactions. 5. Kinetics of the Oxidation of Ethylenediaminetetraacetatocobaltate(II) Complexes by Peroxodisulfate Ion, Induced by Irradiation with Visible Light of Aqueous Solutions Containing Tris(2,2′-bipyridine)ruthenium(II) Ion [O] . Suzuko Nishida, Masaru Kimura 1987

机译：光诱导的电子转移反应。 5.通过过脱氧离子离子氧化乙二胺四乙酰钴钴酸钴酸酯（II）配合物的动力学，通过含有Tris（2,2'-吡啶）钌（II）离子的水溶液的可见光辐射诱导
8. Oxidative and Electrophilic Pathways in the Reactions of Organochromium(III) Complexes with Nitrous Acid and Tris(2,2'-Bipyridyl) Ruthenium(III) [R] . Melton, J. D. 1986

机译：有机铬（III）配合物与亚硝酸和三（2,2'-联吡啶）钌（III）反应中的氧化和亲电通路

Kinetics and mechanism of the oxidation of glyoxylic acid by peroxodisulfate induced by irradiation with visible light of aqueous solutions containing tris (2,2'-bypyridine)ruthenium(II) ion

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