Photocatalytic degradation kinetics and mechanisms of antibacterial triclosan in aqueous TiO_2 suspensions under simulated solar irradiation

摘要

BACKGROUND: The present study focuses on the photocatalytic transformation and mineralization of triclosan (TCS) using TiO_2 catalyst. The main objectives were: (a) to investigate the effect of TiO_2, TCS concentration and irradiation intensity on the photocatalytic efficiency and to model the degradation and mineralization percentage of TCS using response surface methodology (RSM) based on central composite design (CCD); (b) to identify transformation products (TPs) and degradation mechanisms, (c) to assess the toxicity of the TPs. RESULTS: The results from the RSM analysis indicated that all operating parameters studied have significant effects on TCS degradation and mineralization. A quadratic response surface model was found to fit the experimental data and was used to find the optimum experimental conditions. Scavenging experiments indicated thatHO? radicalswere principally responsible for TCS degradation. The transformation of TCS involved reactions ofmono- and di- hydroxylation, dechlorination, and cleavage of the ether bond. Total detoxification of the treated solution was obtained after 30min, as revealed byMicrotox bioassay. CONCLUSION: TCS can be effectively degraded and mineralized using TiO_2 under simulated solar light avoiding the formation of highly toxic TPs. RSM modeling provided a statistically accurate prediction of the optimum degradation and mineralization of TCS.