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Metal complexes of maleimide compounds

机译:马来酰亚胺化合物的金属配合物

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摘要

The metal complexation ability of some N-substituted maleimides containing a carboxyl group was investigated. Thus, N-(4-carboxy-phenyl)-maleimide, N-(3-acetoxy-4-carboxy-phenyl)-maleimide and poly [N-(3-acetoxy-4-carboxy-phenyl)-maleimide] were prepared and complexed with several transition metals, such as Co2+, Ni2+ and Cu2+. The formation of complexes which separated as precipitates from the reaction mixtures was confirmed by elemental and spectral analyses. The thermal stability of the complexes was evaluated by thermogravimetry.
机译:研究了一些含羧基的N-取代马来酰亚胺的金属络合能力。因此,制备了N-(4-羧基-苯基)-马来酰亚胺,N-(3-乙酰氧基-4-羧基-苯基)-马来酰亚胺和聚[N-(3-乙酰氧基-4-羧基-苯基)-马来酰亚胺]。并与几种过渡金属(例如Co2 +,Ni2 +和Cu2 +)络合。通过元素分析和光谱分析证实了从反应混合物中以沉淀形式分离出的络合物的形成。配合物的热稳定性通过热重法评估。

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