Electronic thermal conductivity and thermopower of armchair graphene nanoribbons

摘要

A theoretical investigation of the diffusion contribution to thermopower, S_d, and the electronic thermal conductivity, k_e, of semiconducting armchair graphene nanoribbons (GNRs) is made for T ≤ 300 K. Considering the electrons to be scattered by edge roughness, impurities and deformation-potential coupled acoustic phonons and optical phonons, expressions for S_d and k_e are obtained. Numerical calculations of S_d and k_e, as functions of temperature and linear carrier density, bring out the relative importance of the contributing scattering mechanisms. A GNR of width 5 nm, supporting an electron density 2 x 10~8 m~(-1) is found to exhibit room temperature values of S_d and k_e as 42 μV/K and 26.5 W/mK, respectively. A decrease in armchair GNR width, is found to enhance S_d and reduce k_e. The effect of varying the electron density is to increase their magnitude when Fermi energy moves into the second subband. An analysis of thermopower and thermal conductivity data in clean armchair GNR samples will enable better understanding of the electron-phonon interaction.