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首页> 外文期刊>The Journal of Chemical Physics >Wetting of a fluid interface by a homopolymer: A system with a rich prewetting behavior
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Wetting of a fluid interface by a homopolymer: A system with a rich prewetting behavior

机译:用均聚物润湿流体界面:具有丰富的预润湿行为的系统

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A lattice-based self-consistent-field theory is used to reveal the wetting characteristics of a polymeric phase at an interface between two solvent phases. Both solvents are monomeric and the polymer chains are modeled as freely jointed chains of N = 100 similar segments. From the polymer point of view we limit our investigations to the symmetric case; both solvents are equally poor for the polymer. We show that the polymer wets the interface both in the limit of strongly and weakly segregated liquids, but that at intermediate values of the L/L demixing the polymer phase can be in a lens configuration (partial wetting). The wetting transitions at strong segregation of the two solvents is always first order, the ones at weak segregation can be either first or second order, depending on the polymer/solvent interactions. For a particular value of the polymer-solvent interaction parameter the two wetting transitions as generated by changing the L/L demixing (then both of the first-order type) merge. At this point the two prewetting lines still exist and obviously merge as well. It is further possible to find detached "prewetting" lines in the regime where the polymer wets the interface at all relevant (i.e., consistent with the presence of three phase coexistence) values of the L/L demixing. Physically this means that there is a range of interfacial widths for which the formation of a new (polymeric) phase is hindered by a free energy barrier at a certain film thickness, but that there is no wetting transition associated with this barrier.
机译:基于晶格的自洽场理论用于揭示聚合物相在两个溶剂相之间的界面处的润湿特性。两种溶剂均为单体,聚合物链建模为N = 100个相似链段的自由连接链。从聚合物的角度来看,我们的研究限于对称情况。两种溶剂对聚合物均同样不良。我们表明,聚合物在强和弱隔离液体的极限内都润湿界面,但是在L / L分解的中间值时,聚合物相可能处于透镜配置(部分润湿)状态。两种溶剂在强偏析下的润湿转变始终是一阶的,弱偏析下的润湿转变可以是一阶或二阶的,具体取决于聚合物/溶剂的相互作用。对于特定的聚合物-溶剂相互作用参数值,通过更改L / L混合(然后是一阶类型)生成的两个润湿过渡合并。此时,两条预润湿线仍然存在,并且显然也合并了。在聚合物在L / L混合的所有相关的(即,与三相共存的存在一致的)值润湿界面的方案中,还可能找到分离的“预润湿”线。从物理上讲,这意味着存在一定范围的界面宽度,在一定的薄膜厚度下,新的(聚合物)相的形成会受到自由能势垒的阻碍,但是没有与该势垒相关的润湿转变。

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