Reaction of 2-Germanaphthalene with Elemental Sulfur and Selenium: Synthesis of Novel Cyclic Polychalcogenides Containing a Germanium, Trichalcogenageromolanes

摘要

Novel five-membered cyclic trichalcogenides containing a germanium atom were synthesized by the reactions of a kinetically stabilized 2-germanaphthalene with elemental sulfur and selenium, and the molecular structure of the triselenide was determined by X-ray crystallographic analysis.